Microwave Assisted Synthesis Of Modified Methyl Esters And Its Application Into Formulation Of Detergents

  IJETT-book-cover  International Journal of Engineering Trends and Technology (IJETT)          
  
© 2019 by IJETT Journal
Volume-67 Issue-10
Year of Publication : 2019
Authors : Madhura Bhalerao, Dr. Vijay Y Karadbhajne
  10.14445/22315381/IJETT-V67I10P207

MLA 

MLA Style: Madhura Bhalerao, Dr. Vijay Y Karadbhajne  "Microwave Assisted Synthesis Of Modified Methyl Esters And Its Application Into Formulation Of Detergents" International Journal of Engineering Trends and Technology 67.10 (2019):38-42 

APA Style: Madhura Bhalerao, Dr. Vijay Y Karadbhajne. Microwave Assisted Synthesis Of Modified Methyl Esters And Its Application Into Formulation Of Detergents  International Journal of Engineering Trends and Technology, 67(10),38-42.

Abstract
Microwave energy is a unique source because it creates heat deep within the material being processed. This property results in much shorter process time, higher yield of finished product and better quality than conventional processing.Microwave interacts with dielectric material to generate heat by the agitation of molecule in a alternating electromagnetic field.The unique property of microwave to penetrate deeply into material of interest reduces the process time, often by much as 10 to 1 and it reduces the cost of processing. Space saving is other reason for choosing microwave. Long stretched processing line can be compressed into a fraction of space. Thus it reduces the cost of construction & substantial economic saving. Modified Methyl Ester(MME) was synthesised at optimum temperature and input power of microwave which has the acid value and HLB ratio of the sample MME as 67.11 and 12.24 and is hence best suitable as an active ingredient for powder detergent..

Reference

[1] Corsaro, A., Chiacchio, U., Pistarj, V. and Romeo, G., ―Microwave-assisted Chemistry of Carbohydrates, Current Organic Chemistry, 2004, 8, Page No. 511-538.
[2] Brown, S.L., Rayner, C. M., Graham, S., Cooper, A., Rannard, S. and Perrier. S., ―Ultra-fast microwave enhanced reversible addition-fragmentation chain transfer (RAFT) polymerization: monomers to polymers in minutes, Chemical Communications, 2007, Page No. 2145 – 2147.
[3] Zhang, C., Liao, L. and Gong, S., ―Recent developments in microwave-assisted polymerization with a focus on ring-opening polymerization‖, Green Chemistry, 2007, 9, Page No. 303-314.
[4] Jermolovicius, L.A., Schneiderman, B., Senise, J.T., de Castro,E.R.,―Microwaves synergic effect on maleic anhydride catalytic esterification with 2-ethylhexanol-1, Microwave and Optoelectronics Conference, Sept. 2003, 759- 764.
[5] Liu, L., Li, Y., Fang, Y. and Chen, L., ―Microwave-assisted graft copolymerization of ε-caprolactone onto chitosan via the phthaloyl protection method, Carbohydrate Polymers, 25 May 2005, 60, Page No. 351-356
[6] Bhalerao M.,et. al. “A kinetic study on malenisation of soybean oil”, IJIERT, Vol. (2),feb 2018.
[7] Madhura B ,et.al. “ A Kinectic study on Malenised Castor Oil (Ricinus Communis)” , IRJMST ,Vol 9 , Issue 4 ,2018 ,pp 120-129
[8] Madhura B, et.al., “Chemical Reaction Engineering on Isomerisation of Oleic Acid : Clay Catalyst” , IJIERT , VOL 5 ,Issue 6 , June 2018.
[9] Pang, K., Kotek, R. and Tonelli, A., ―Review of conventional and novel polymerization processes for polyesters, November 2006, 31, Page No. 1009- 1037
[10] Tomanová, V., Pielichowski, K., Sroková, I., Žoldaková, A., Sasinková, V. and Ebringerová, A., ―Microwave-assisted synthesis of carboxymethylcellulose - based polymeric surfactants, Polymer Bulletin, September 20, 2007, page No. 451
[11] Hoogenboom, R., Schubert, U. S., ―Microwave-Assisted Polymer Synthesis: Recent Developments in a Rapidly Expanding, Macromolecular Rapid Communications, 21 Feb 2007, 28, Page No. 368 – 386
[12] Wiesbrock, F., Hoogenboom, R., Schubert, U. S., ―Microwave-AssistedPolymer Synthesis: State-of-the-Art and Future Perspectives, Macromolecular Rapid Communication, 2004, 25, Page No. 1739-1764.
[13] Bhalerao M, Karadbhajne V Y , “Polymeric Surfactants : Evolution and Review” , International Journal of ChemTech ,Vol. 12 (01) , Dec 2018.
[14] Senadeera, G. K. R., ―Microwave-assisted steps in the synthesis of poly (3-thiophenylacetic acid), Current Science, 10 January 2005, 88, Page No. 145-148.
[15] Brittany L. Hayes, ―Microwave Synthesis Chemistry, CEM Publication, 2002, Page No. 11-25.

Keywords
microwave heating , yield , modified methyl ester ,powder detergent ,process time