Thermal Cycle Testing of a few Selected Inorganic Salts as Latent Heat Storage Materials for High- Temperature Thermal Storage

Thermal Cycle Testing of a few Selected Inorganic Salts as Latent Heat Storage Materials for High- Temperature Thermal Storage

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© 2021 by IJETT Journal
Volume-69 Issue-8
Year of Publication : 2021
Authors : Abdullahi Bello Umar, Mukesh Kumar Gupta, Dharam Buddhi
DOI :  10.14445/22315381/IJETT-V69I8P203

How to Cite?

Abdullahi Bello Umar, Mukesh Kumar Gupta, Dharam Buddhi, "Thermal Cycle Testing of a few Selected Inorganic Salts as Latent Heat Storage Materials for High- Temperature Thermal Storage," International Journal of Engineering Trends and Technology, vol. 69, no. 8, pp. 17-25, 2021. Crossref, https://doi.org/10.14445/22315381/IJETT-V69I8P203

Abstract
Thermal cycling test was conducted for 50 cycles to determine the suitability of some commercialgrade phase change materials (PCMs) for solar thermal latent heat storage in terms of melting temperature, latent heat of fusion, and thermal stability. Four samples comprising of three single inorganic salts (NaNO3 and KNO3), one binary (KNO3/KCl), and one ternary (MgCl2/NaCl/KCl) eutectic were studied. It was discovered that all the samples have melting temperatures near the manufacturer`s quoted temperatures. However, the latent heat varies significantly for some and perfectly for sodium nitrate (NaNO3) and nearly for potassium nitrate (KNO3). In terms of stability, the Thermogravimetric analysis (TGA) test conducted indicates that all the tested PCMs are stable and after undergoing so many thermal cycles.

Keywords
Thermal cycle, PCM, Eutectics, Energy storage, solar power plant.

Reference
[1] Guruprasad Alva, Lingkun Liu, Xiang Huang, Guiyin Fang., Thermal energy storage materials and systems for solar energy applications, Renewable and Sustainable Energy Reviews, 68 (2017) 693–706
[2] Bruno Cárdenas, Noel León., High-temperature latent heat thermal energy storage: Phase change materials, design considerations, and performance enhancement techniques, Renewable and Sustainable Energy Reviews, 27 (2013) 724–737
[3] Marc Medrano, Antoni Gil, Ingrid Martorell, Xavi Potau, Luisa F. Cabeza., State of the art on high-temperature thermal energy storage for power generation. Part 2—Case studies, Renewable and Sustainable Energy Reviews, 14 (2010) 56–72
[4] Ming Liu, Wasim Saman, Frank Bruno., Review on storage materials and thermal performance enhancement techniques for high-temperature phase-change thermal storage systems. Renewable and Sustainable Energy Reviews, 16 (2012) 2118– 2132
[5] Doerte Laing, Thomas Bauer, Nils Breidenbach, Bernd Hachmann, Maike Johnson, Development of high temperature phase-change-material storages, Applied Energy, 109 (2013) 497–504
[6] Shamseldin A. Mohamed et al., A review on current status and challenges of inorganic phase change materials for thermal energy storage systems, Renewable and Sustainable Energy Reviews, 70 (2017) 1072–1089
[7] D. Zhou, C.Y. Zhao, Y. Tian,., Review on Thermal Energy Storage with Phase Change Materials (PCMs) in Building Applications, Applied Energy, 92 (2012) 593–605
[8] S. Sami., Prediction of Behavior of Thermal Storage, PVThermal Solar Collector with Nanofluids and Phase Change Material. IJETT International Journal of Thermal Engineering 6(1) (2020) 11-27.
[9] V.V. Tyagi and D. Buddhi., Thermal cycle testing of calcium chloride hexahydrate as a possible PCM for latent heat storage, Solar Energy Materials & Solar Cells, 92 (2008) 891– 899
[10] A Shukla, D Buddhi, RL Sawhney., Thermal cycling test of few selected inorganic and organic phase change materials, Renewable Energy 33 (12) (2008) 2606-2614.
[11] A Sharma, SD Sharma, D Buddhi., Accelerated thermal cycle test of acetamide, stearic acid, and paraffin wax for solar thermal latent heat storage applications. Energy Conversion and Management 43 (14) (2002) 1923-1930.
[12] S. D Sharma, D Buddhi, RL Sawhney., Accelerated thermal cycle test of latent heat-storage materials, Solar Energy 66 (6) (1999) 483-490.
[13] A Sharma, SD Sharma, D Buddhi, RL Sawhney., Thermal cycle test of urea for latent heat storage applications, International journal of energy research 25(5) (2001) 465-468
[14] Zalba B, Marín JM, Cabeza LF, Mehling H., Review on thermal energy storage with phase change: materials, heat transfer analysis and applications. Appl. Therm. Eng, 23 (3):25 (2003) 1- 83.
[15] Bejan Adria, Entropy generation minimization: The method of thermodynamic optimization of finite size systems and finite-time processes. CRC Press; (1996), http://dx.doi.org/10.1063/1.362674
[16] Hoshi A, Mills DR, Bittar A, Saitoh TS., Screening of high melting point phase change materials (PCM) in solar thermal concentrating technology based on CLFR. Sol Energy 79 (2005)332–9.
[17] Liu M, Gomez JC, Turchi CS, Tay NHS, Saman W, Bruno F., Determination of thermo-physical properties and stability testing of high-temperature phase change materials for CSP applications. Sol Energy Mater Sol Cells, 139 (2015) 81–7.
[18] Lane GA., Phase change materials for energy storage nucleation to prevent supercooling. Sol Energy Mater Sol Cells, 27 (1992) 135–60.
[19] G. Suganya, D. Nanda Kumar.M,., Analysis of Latent Heat Thermal Energy Storage System Using Phase Change Material IJETT International Journal of Mechanical Engineering, 8(3) (2021) 5-10.
[20] Murat M K., High-temperature phase change materials for thermal energy storage, Renewable and Sustainable Energy Reviews, 14 (2010) 955–970
[21] Thomas Bauer, Doerte Laing, and R. Tamme, Characterisation of Sodium Nitrate as Phase Change Material, Int. Journal of Thermophysics, 33 (2012) 91-104.
[22] Horst Michels, Robert Pitz-Paal., Cascaded latent heat storage for parabolic trough solar power plants, Solar Energy, 81 (2007) 829–837
[23] Tamme, R., Concrete storage: update on the German concrete TES program. In: Proceedings of Workshop on Thermal Energy Storage for Trough Power Systems, Golden (Colorado), USA, February, (2003) 20–21.
[24] Yong Deng, Jinhong Li, Tingting Qian, Weimin Guan, Xiang Wang, Preparation and Characterization of KNO3/diatomite Shape-stabilized Composite Phase Change Material for High- Temperature Thermal Energy Storage, Journal of Materials Science & Technology, (2016). http://dx.doi.org/doi: 10.1016/j.jmst.2016.02.011.
[25] Bauer, T., Pfleger, N., Laing, D., Steinmann, W-D., Eck, M., Kaesche, S.,a. High-Temperature Molten Salts for Solar Power Application, in Molten Salts Chemistry, Elsevier, (2013).
[26] Bauer, T., Pfleger, N., Breidenbach, N., Eck, M., Laing, D., Kaesche, S. , b. Material aspects of Solar Salt for sensible heat storage, Applied Energy, 111 (2013) 1114-1119.
[27] Cordaro, J.G., Kruizenga, A.M., Altmaier, R., Sampson, M., Nissen, A. , Thermodynamic Properties of Molten Nitrate Salts, SolarPACES (2011).
[28] Benes O., Konings, R.J.M., Wurzer, S., Seirig, M., Dockendorf, A., A DSC study of the NaNO3-KNO3 system using an innovative encapsulation technique. Thermochim. Acta, 509 (2010) 62-66.
[29] Garkushin IK, Trunin AC, Miftakhov TT, Dibirov MA., Salt heat storage composition. USSR Patent 1036734; (1983).
[30] Carolina Villada, Franklin Jaramillo, Juan Guillermo Castano, Felix Echeverria, and Francisco Bolivar, Design and Development of Nitrate-Nitrite based molten salts for Concentrating Solar Power Applications, Solar Energy, 188 (2019) 291-29.