Deterpenation of Orange Essential Oil by Molecular Distillation

  IJETT-book-cover  International Journal of Engineering Trends and Technology (IJETT)          
  
© 2015 by IJETT Journal
Volume-30 Number-4
Year of Publication : 2015
Authors : Miriam A.Martinello, Cecilia L. Pagliero, Carolina A. Allevi
  10.14445/22315381/IJETT-V30P231

MLA 

Miriam A.Martinello, Cecilia L. Pagliero, Carolina A. Allevi"Deterpenation of Orange Essential Oil by Molecular Distillation", International Journal of Engineering Trends and Technology (IJETT), V30(4),161-165 December 2015. ISSN:2231-5381. www.ijettjournal.org. published by seventh sense research group

Abstract
the influence of two operative conditions in the orange essential oil deterpenation by molecular distillation: rotor speed (100-200 rpm) and evaporation temperature (19-33ºC), on oxygenated compounds (linalool) recovery (LR) and on the oxygenated compounds monoterpenes concentration ratio (CR) were studied. A central composite design and the response surface methodology were employed for experimental design and for the molecular distillation process modelling, respectively. It was found that the maximum concentration ratio is obtained at the lowest rotor speed and at an intermediate temperature level while the linalool recovery decreases with temperature and rotor speed. So, the best conditions to achieve a high concentration ratio (CR=10) and an acceptable linalool recovery (LR=65%) are 25ºC for evaporation temperature and 100 rpm for rotor speed. Higher concentration ratios could be obtained only if oxygenated compounds recovery is resigned.

 References

[1] F. Buccellato, ―Citrus Oils in Perfumery and Cosmetic Products. Perfumer & Flavorist, vol. 25, pp. 59-63, 2000.
[2] R. Wildman, Handbook of Nutraceuticals and Functional Foods. CRC Press, USA, 2001.
[3] R. Sanchez, J. Pino, L. Chang, E. Roncal, E. Rogert, ―Desterpenación de aceite esencial de naranja por extracción con etanol diluido, Alimentaria 249, pp. 59-63, 1994.
[4] J. Owusu-Yaw, R.F. Matthews, P. F. West,―Alcohol Deterpenation of Orange Oil, J. Food Sci., vol. 51, pp.1180-1182, 1986.
[5] E. Haypek, E., L.H.M Silva, E. Batista, D.S. Marques, M. A. A., Meirelles, A.J. Meirelles, ―Recovery of aroma compounds from orange essential oil, Braz. J. Chem. Eng. vol 17,pp. 4-7, 2000.
[6] G. Stuart, D. Lopes, V. Oliveira, Deterpenation of Brazilian Orange Peel Oil by Vacuum Distillation, J. Am. Oil Chem. Soc. , vol 78, pp.1041- 1044 , 2001.
[7] P. Dugo, L. Mondello, K.D. Bartle, A. A Clifford, D. G, Breen, G. Dugo, ―Deterpenation of Sweet Orange and Lemon Essential Oils with Supercritical Carbon Dioxide using Silica Gel as an Adsorbent, Flavour Fragrance J., vol. 10, pp. 51-58, 1995.
[8] M. Budich, S. Heilig, T. Wesse, V. Leibküchler, G. Brunner, Countercurrent deterpenation of citrus oils with supercritical CO2, J. Supercrit. Fluids, vol. 14, pp.105-114, 1999.
[9] S. Diaz, S. Espinosa, E.A. Brignole, ―Citrus peel oil deterpenation with supercritical fluids: Optimal process and solvent cycle design, J. Supercrit. Fluids, vol. 35, pp. 49-61, 2005.
[10] O. J Ferrer, R. F. Matthews, ―Terpene reduction in cold pressed orange oil by frontal analysisdisplacement adsorption chromatography. J. Food Sci., vol. 52, pp. 801-805, 1987.
[11] J. D Vora, R.F. Matthews, P.G. Crandall, R. Cook, ―Preparation and chemical composition of orange oil concentrates, J. Food Sci, vol. 48, pp. 1197-1199, 1983.
[12] F. Tateo,Production of concentrated orange oil using thin evaporator, J. Essential Oil Res., pp.7-13, 1990.
[13] M. A. Ferhat, B. Y. Meklati, J.Smadja, F. Chemat, ―An improved microwave Clavenger apparatus for distillation of essential oils from orange peel, J. Chromatogr., A, vol. 1112, pp. 121-126, 2006.
[14] A.Weissberger, Destillation under high vacuum in technique of organic chemistry. Part 1: Distillation, Interscience Publishers, 1951.
[15] R. Perry, D. Green, J. Maloney, Perry´s Chemical Engineers´ Handbook, Sixth Ed., McGraw Hill, 1984.
[16] N. Kumar, P. K. Jhinge, ―Effect of segmental baffles at different orientation on the performance of single pass shell and tube heat exchanger, Int. Journal of Ing. Trends and Technology, vol. 15, pp. 423-428, Sept. 2014.
[17] A. Kannan, S. Kelathoor, ―Mechanical agitation of bed in a motor driven two-phase fluidized bed particle seeder,, Int. Journal of Ing. Trends and Technology, vol. 10, pp. 4383-4387, Oct. 2013.
[18] F. Chen, T. Cai, G. Zhao, X. Liao, L. Guo, X. Hu, ―Optimizing conditions for the purification of crude octacosanol extract from rice bran wax by molecular distillation analysed using response surface methodology, J. Food Eng., vol. 70, pp. 47-53, 2005.
[19] P. F. Martin, V.M Ito, C.B.Batistella,M.R.W. Maciel, ―Free fatty acid separation from vegetable oil deodoriser distillate using molecular distillation process, Sep. Purif. Technol., vol. 48, pp.78-84, 2006.
[20] L. R. Posada, J. Shi, Y. Kakuda, S. J. Xue, ―Extraction of tocotrienols from palm fatty acids distillates using molecular distillation, Sep. Purif. Technol. vol. 57, pp. 220-229, 2007.
[21] P. Shao, S.T. Jiang, Y.J. Yiang, ―Optimization of molecular distillation for recovery of tocopherol from rapeseed oil deodorizer distillate using response surface and artificial neural network models, Trans IChemE, Part C , vol. 85, pp. 85-92, 2007.
[22] L. V., Fregolente, P. B. L., Fregolente, A.M. Chicuta, C. B. Batistella, R. Maciel Filho, M R. Wolf Maciel, ‖Effect of operating conditions on the concentration of monoglycerides using molecular distillation, Trans IChem, Part A , vol. 85, pp. 1524-1528, 2007.
[23] J. Cvengros,Physical Refining of Edible Oils. J. Am. Oil Chem. Soc., vol. 72, pp. 1193-1196, 1995.
[24] M., Martinello, G. Hecker, , M. Pramparo, ―Grape seed oil deacidification by molecular distillation: Analysis of operative variables influence using the response surface methodology, J. Food Eng., vol. 81, pp. 60-64, 2007.
[25] W. Wu, C. Wang, J. Zheng, ―Optimization of deacidification of low-calorie cocoa butter by molecular distillation, LWT-Food Sci. Technol., vol. 46, pp. 563-570, 2012.
[26] Å. Oterhals, B. Kvamme, M. Berntssen, ―Modeling of a short-path distillation process to remove persistent organic pollutants in fish oil based on process parameters and quantitative structure properties relationships, Chemosphere, vol. 80, pp. 83–92, 2010.
[27] S. Zeboudj, N. Belhaneche-Bensemra, R. Belabbes, ―Use of surface response methodology for the optimization of the concentration of the sweet orange essential oil of Algeria by wiped film evaporator, J. Food Eng., vol. 67, pp. 507-512, 2005.
[28] L. P. Tovar, M. R. Wolf Maciel, G. M. Ferreira Pinto, R. Maciel Filho, D. Ramalho Gomes, ―Factorial Design applied to concentrate bioactive component of Cymbopogon citratus essential oils using short path distillation, Chem. Eng. Res.& Des., vol. 88, pp. 239- 244, 2010.
[29] J. A. Di Rienzo, F. Casanoves, M. G. Balzarini, L. Gonzalez, M. Tablada,C. W Robledo,. Software InfoStat., Universidad Nacional de Córdoba, Argentina, 2011.

Keywords
Molecular distillation, orange essential oil, response surface methodology, deterpenation.