Preparation of Poly(3HT - Co - TH) - PMMA Polymer Blend Films and Study Their Optical Properties

  IJETT-book-cover  International Journal of Engineering Trends and Technology (IJETT)          
  
© 2020 by IJETT Journal
Volume-68 Issue-12
Year of Publication : 2020
Authors : Imad Al - Deen Hussein Ali Al - Saidi, Hussein Falih Hussein, Numan Sleem Hashim
DOI :  10.14445/22315381/IJETT-V68I12P213

Citation 

MLA Style: Imad Al - Deen Hussein Ali Al - Saidi, Hussein Falih Hussein, Numan Sleem Hashim. Preparation of Poly(3HT - Co - TH) - PMMA Polymer Blend Films and Study Their Optical Properties International Journal of Engineering Trends and Technology 68.12(2020):72-76. 

APA Style:Imad Al - Deen Hussein Ali Al - Saidi, Hussein Falih Hussein, Numan Sleem Hashim. Preparation of Poly(3HT - Co - TH) - PMMA Polymer Blend Films and Study Their Optical Properties.  International Journal of Engineering Trends and Technology, 68(12), 72-76.

Abstract
Poly(3HT - Co - Th) - PMMA polymer blend films at different percentage weight ratios of the copolymer poly(3HT - Co - Th) were prepared using the casting method. Their optical properties were studied. The copolymer poly(3HT - Co - Th) was prepared using the addition method, where thiophene was added to 3 - hexylthiophene in the presence of FeCl3 at room temperature. Then, the polymer blend poly(3HT - Co - Th) - PMMA was prepared by the addition of the prepared copolymer to the poly(methylmethacrylate) (PMMA) polymer. The optical absorbance (A) and transmittance (T) spectra of the prepared polymer blend films were measured over the wavelength range 300 - 800 nm for different weight ratios of the copolymer poly(3HT- Co - Th) using a UV - Visible double - beam spectrophotometer. The optical parameters of the poly(3HT- Co - Th) - PMMA polymer blend films, the real part (?r) and the imaginary part of the dielectric constant (?), and the optical energy bandgap (Eg) were determined. The obtained results indicate that the prepared polymer blend poly (3HT- Co - Th) - PMMA films promise practical applications in photonic and optoelectronic devices.

Reference
[1] R. L. Byer, Nonlinear Optical Phenomena and Materials (Stanford University, California, USA, 1974).
[2] T. Kobayashi, (Ed.), Nonlinear Optics of Organics and Semiconductors, Springer Proceedings in Physics, Vol.36, (Springer-Verlag, Berlin, Germany, 1989).
[3] B. E. A. Saleh and M. C. Teich, "Nonlinear Optics, in Fundamentals of Photonics, (John Wiley and Sons, Inc., Hoboken, USA, 1991).
[4] J. Zyss, (Ed.), Molecular Nonlinear Optics: Materials, Physics, Devices, (Academic Press, Inc, New York, USA, 1994).
[5] J. D. Bhawalkar, G. S. He, and P. N. Prasad, Nonlinear Multiphoton Processes in Organic and Polymeric Materials, Rep. Prog. Phys., 59 (9), (1996), 1041 - 1070.
[6] A. Dakshanamoorthy, Fundamental of Nonlinear Optical Materials, Pramana, 57 (5), (2001), 871 - 883.
[7] D. Y. Kim, H. N. Cho, and C. Y. Kim, Blue Light Emitting Polymers. Prog. Polymer Sci. 25 (8) (2000), 1089 - 1139.
[8] S. C. Lo and P. L. Burn, Development of Dendrimers: Macromolecules for Use in Organic Light-Emitting Diode and Solar Cells, Chemical. Reviews, 107 (4) (2007), 1097 -1116.
[9] N. Costa and A. Cartaxo (Eds.), Advances in Lasers and Electro - Optics, (InTech, Rijeka, Croatia, 2010).
[10] Imad Al-Deen Hussein A. Al-Saidi and Saif Al-Deen Abdulkareem, Study of Nonlinear Optical Properties and Optical Power Limiting of Leishman Dye Using Z-Scan Technique, Indian J. Phys., 89 (11) (2015), 1199 - 1203.
[11] Imad Al-Deen Hussein Ali Al-Saidi and Raghad Jabar Investigation of Optical Properties of Solochrome Dark Blue Dye Doped Polymer Films, J. Mater. Phys. Chem., 5 (1) (2017), 32 - 38.
[12] Imad Al-Deen Hussein Ali Al-Saidi, Hussein Falih Hussein and Arafat Hady Kareem, Preparation and Optical Properties Characterization of P3OT - PMMA Polymer Blend Films Intern. J. of Research - Granthaalayah, 7 (10) (2019), 238 - 246.
[13] O. Ostroverkhova, (Ed.), Handbook of Organic Materials for Optical and Optoelectronic Devices: Properties and Applications, 1st Edition, (Woodhead Publishing Ltd., UK, 2013).
[14] S. Kasap and P. Capper, (Eds.), Springer Handbook of Electronic and Photonic Materials (Springer-Verlag, Berlin, Germany, 2017).
[15] O. Ostroverkhova, (Ed.), Handbook of Organic Materials for Electronic and Photonic Devices, 2nd Edition, (Woodhead Publishing Ltd., UK, 2018).
[16] J. R. Reynolds, B. C. Thompson, and T. A. Skotheim, (Eds.), Handbook of Conducting Polymers, 4th Edition, 2- Volume Set, (CRC Press, Boca Raton, Florida, USA, 2019).
[17] R. O. Ebewele, Polymer Science and Technology, (CRC Press, Boca Raton, Florida, USA, 2000).
[18] L. H. Sperling, Introduction to Physical Polymer Science (John Wiley and Sons, Inc., Hoboken, USA, 2006).
[19] M. E. Nicho, D. Pena-Salgado, and P. Altuzar - Coello, Morphological and Physicochemical Properties of Spin - Coated Poly(3-Octylthiophene) / Polystyrene Composite Thin Films, Thin Solid Film, 518 (7) (2010), 1799 - 1803.
[20] C. Fleischmann, M. Lievenbrück, and H. Ritter, Polymers, and Dyes: Developments and Applications, Polymers, 7 (4) (2015), 717 - 746.
[21] N. F. Mott and A. E. Davis, Electronic Process in Non - Crystalline Materials, 2nd Edition, (University Press, Oxford, UK, 1979).
[22] D. E. Gray, (Ed.), American Institute of Physics Handbook, 3rd Edition, (McGrow Hill Book Co., New York, USA, 1982).
[23] J. I. Pankove, Optical Processes in Semiconductors (Prentice-Hall, New York, USA, 1971).
[24] T. S. Moss, Optical Properties of Semiconductors (Academic Press, New York, USA, 1974).
[25] I. Eckertova, Physics of Thin Films, 2nd Edition, (Plenum Press, New York, USA, 1986).
[26] M. S. Dresselhaus, Optical Properties of Solids, Solid State Physics Part II, (University of the Pennsylvania state, USA, 1998).
[27] J. Tauc, (Ed.), Amorphous and Liquid Semiconductors, Vol. 159 (Plenum Press, New York, USA, 1974).

Keywords
Thiophene, Copolymer, Polymer Blend Films, Optical Properties, Optical Energy Band Gap.