Elementary vs. Advanced techniques: A Comparative Approach to Examine Various Types of Blue Inks

Elementary vs. Advanced techniques: A Comparative Approach to Examine Various Types of Blue Inks

  IJETT-book-cover           
  
© 2021 by IJETT Journal
Volume-69 Issue-11
Year of Publication : 2021
Authors : Mandeep Kaur Purba, Shruti Gupta, Reeta Rani Gupta
DOI :  10.14445/22315381/IJETT-V69I11P222

How to Cite?

Mandeep Kaur Purba, Shruti Gupta, Reeta Rani Gupta, "Elementary vs. Advanced techniques: A Comparative Approach to Examine Various Types of Blue Inks," International Journal of Engineering Trends and Technology, vol. 69, no. 11, pp. 170-179, 2021. Crossref, https://doi.org/10.14445/22315381/IJETT-V69I11P223

Abstract
Forensic document examiners` wide range of tasks incorporate the expertise to determine the origin of penmanship of the document; segregate among authentic, imitated or disguised penmanship; analyze components and characteristics of inks, papers, and different materials associated with documents. The present study focuses on the comparative aspects between various simplified techniques used for blue pen ink examination with advanced instrumental techniques such asSEM and SEM-EDX. The samples were analyzed primarily for different types of alterations, overlapping of ink, and composition of ink initially by using preliminary techniques followed by advanced instrumental techniques. The examination of ink led to unexpected and astonishing results. In spite of advancements in technology, the success rate of simplified techniques was found to be higher than 90% for all the parameters studied, that is, alterations, obliterations, and overlapping of ink, whereas advanced instrumental techniques did not ascertain to be of much use except for the determination of the composition of the ink. Even in today’s advanced digital age, selected simplified techniques have proved to be reliable and gave easily reproducible results for the detection of alterations and overlapping of ink. Nonetheless, the combination of simplified and advanced instrumental techniques can also be used for the determination of the composition of the ink. This article provides an insight to the examiners to select the best suitable non-destructive technique/s and conduct the examination accordingly.

Keywords
Questioned documents; ink examination; hand lens, light sources; UV chamber; SEM-EDX

Reference
[1] Koppenhaver KM. Forensic document examination: principles and practice.Humana Press, Totowa (NJ). (2010).
[2] Nandini N S, Ajay R. A Study on the impact of Forensic Audit towards Investigation and Prevention of Frauds. Asian Journal of Management. 12(2) (2021) 186-2. doi: 10.52711/2321-5763.2021.00028
[3] Hamilton C. Hitler`s Diaries in the Headlines. In: The Hitler diaries: fakes that fooled the world. University Press of Kentucky.(2015).
[4] Neumann C., Margot P. New perspectives in the use of ink evidence in forensic science: Part I, Development of a quality assurance process for forensic ink analysis by HPTLC. Forensic Science International., 185(1-3) (2009) 29-37. doi: 10.1016/j.forsciint.2008.11.016.
[5] Purba MK, Gupta S., Gupta RR, et al. A survey of techniques used for Ink examination. Journal of Punjab Academy of Forensic Medicine and Toxicology. 19(1) (2019) 155-161.doi: 10.5958/0974-083X.2019.00032.3
[6] Ferreira P.et al.Forensic analysis of ballpoint pen inks using paper spray mass spectrometry. Analyst. 140 (2015) 811-819. doi: 10.1039/c4an01617c
[7] Amador VSet al., Paper Spray Mass Spectrometry for the Forensic Analysis of Black Ballpoint Pen Inks. Journal of American Society of Mass Spectrometry. 28(9) (2017) 1965-1976. doi: 10.1007/s13361-017-1686-z
[8] Kiran.Analysis of commonly used blue ballpoint pen ink in India by Planar Chromatography. International Journal of Advanced Research. 5(7) (2017) 981-988. doi:10.21474/IJAR01/480
[9] Brunelle RL, Kenneth RC.Advances in the forensic analysis and dating of writing ink.CC Thomas, Springfield, Illinois (USA).(2003)
[10] Brunelle RL, Robert RW.Forensic examination of ink and paper. CC Thomas, Springfield; Illinois USA. (1984).
[11] Upadhyay S., Fatima. Research Journal of Pharmacy and Technology. 10(12) (2017) 4209-4210.doi: 10.5958/0974-360X.2017.00769.7
[12] Idris M., Shukla S.K., Baggi T.R. Interference Study on Artificial Sweeteners in Forensic Toxicological Screening by TLC. Asian Journal of Research in Chemistry. 4(3) (2011) 419-422.
[13] Salunke P.A. et al. Separation of Dyes by Mixed Hydrotropic Thin Layer Chromatography. Asian Journal of Pharmaceutical Analysis. 9(3) (2019) 151-155. doi: 10.5958/2231-5675.2019.00027.9
[14] Lee LC et al., Fast and Simple Forensic Red Pen Ink Analysis using Ultra-Performance Liquid Chromatography (UPLC). Malaysian Journal of Analytical Sciences. 20(2) (2016) 224-230. doi:10.17576/mjas-2016-2002-02
[15] Sahu Manju et.al. A Study of Variation in Ball Point Ink of Different Brands by Thin Layer Chromatography. Research Journal of Pharmacy and Technology. 10(12) (2017) 4261-4263.doi: 10.5958/0974-360X.2017.00780.6
[16] Sumithra M., Yuvanesh P., MistryA. Analytical method development and validation of ambroxol hydrochloride by UV spectroscopy and forced degradation study and detection of stability. Research Journal of Pharmacy and Technology. 9(7) (2016) 794-800 . doi: 10.5958/0974-360X.2016.00152.9
[17] Bijithra C., Ragan G., Shanmugasundaram P. Analytical Method Development and Validation of Modafinil in Pure and Tablet Dosage Form by UV Spectroscopy. Research Journal of Pharmacy and Technology. 9(8) (2016) 1303-1308. doi: 10.5958/0974-360X.2016.00202.X
[18] Ghosh S. et al. Inductively Coupled Plasma –Optical Emission Spectroscopy: A Review. Asian Journal of Pharmaceutical Analysis. 3(1) (2013) 24-33.
[19] Rana R., Kumar A., Bhatia R. Impact of Infra-Red Spectroscopy in Quantitative Estimation: An Update. Asian Journal of Pharmaceutical Analysis. 10(4) (2020) 218-230. doi: 10.5958/2231-5675.2020.00040.X
[20] Virani P., Dungrani K. Analytical methods for Irbesartan in bulk drug by Ultraviolet spectroscopy. Asian Journal of Pharmaceutical Analysis. 5(3) (2015) 147-150.
[21] Gautam R.K.et.al. Biosorption of an Acidic Dye, Alizarin Red S, Onto Biosorbent of Mustard husk: Kinetic, Equilibrium Modeling, and Spectroscopic Analysis. Asian Journal of Research in Chemistry. 7(4) (2014) 417-425.
[22] Zi?ba PJ, Kunicki M. Application of the micro-FTIR spectroscopy, Raman spectroscopy, and XRF method examination of inks. ForensicScienceInternational. 158(2-3) (2006) 164-172. doi: 10.1016/j.forsciint.2005.04.044.
[23] Causin Vet.al., The discrimination potential of ultraviolet?visible spectrophotometry, thin-layer chromatography, and Fourier transform infrared spectroscopy for the forensic analysis of black and blue ballpoint inks. Journal of Forensic Science.53(6) (2008) 1468-73. doi: 10.1111/j.1556-4029.2008.00867.x.