Production of Corrosion Inhibitors Based on Crotonaldehyde and their Inhibitory Properties

Production of Corrosion Inhibitors Based on Crotonaldehyde and their Inhibitory Properties

© 2022 by IJETT Journal
Volume-70 Issue-8
Year of Publication : 2022
Authors : Nurilloev Zafar, Beknazarov Khasan, Nomozov Abror
DOI : 10.14445/22315381/IJETT-V70I8P243

How to Cite?

Nurilloev Zafar, Beknazarov Khasan, Nomozov Abror, "Production of Corrosion Inhibitors Based on Crotonaldehyde and their Inhibitory Properties," International Journal of Engineering Trends and Technology, vol. 70, no. 8, pp. 423-434, 2022. Crossref,

This paper studied the synthesis of oligomer-type corrosion inhibitors IKF-1 and IKF-2 based on crotonaldehyde, diamidophosphate and dithioamidophosphate. Therefore, the kinetics of the formation of this corrosion oligomer has been studied. The IR spectra of the obtained oligomer were studied and analyzed. The resulting oligomer was used as a corrosion inhibitor to protect metal structures from H2S corrosion generated in the sulfur gases and petroleum industries. Integration efficiency was considered at different concentrations (100, 200, 300 and 500 mg / l) and temperatures (298 K and 323 K). The results were studied by SEM, EIS, gravimetric method, potentiostat polarization curves and enthalpy adsorption.

Diamidophosphate, Dithioamidophosphate, Croticaldehyde, Oligomer, IKF-1, IKF-2.

[1] Andreatta F., Fedrizzi L. Corrosion Inhibitors / Springer Ser. Mater. Sci. Springer Verlag, vol. 233, pp. 59-84, 2016.
[2] Z. Panossian, N.L.d. Almeida, R.M.F.d. Sousa, G.d.S. Pimenta L.B.S.M, "Corrosion of Carbon Steel Pipes and Tanks by Concentrated Sulfuric Acid: A Review," Corros. Sci, no. 58, pp. 1-11, 2012. Doi:10.1016/j.corsci.2012.01.025
[3] M.M. Osman M.N.S, "Ome Ethoxylated Fatty Acids as Corrosion Inhibitors for Low Carbon Steel in Oil-Field Water," Mater. Chem. Phys, no. 77, pp. 261-269, 2003. Doi:10.1016/S0254-0584(01)00580-6
[4] Magerramov A.M. et al., "Synthesis of Co-Oligomers of 2-Propenylphenol with Maleic Anhydride and Study of Products of their Transformations with Amines as Steel Corrosion Inhibitors, Russ. J. Appl. Chem, Springer, vol. 87, no. 4, pp. 456-460, 2014.
[5] Beknazarov, K. S., Dzhlilov, A. T., Ostanov, U. Y., & Erkaev A.M, "The Inhibition of the Corrosion of Carbon Steel by Oligomeric Corrosion Inhibitors in Different Media," Int. Polym. Sci. Technol, vol. 42, no. 4, pp. 33-37. Doi:10.1177/0307174x1504200406.
[6] Alehyen S. et al., "Preparation of a New Oligomeric Surfactant: N,N,N′,N″,N″-Pentamethyl Diethyleneamine—N,N″-Di- [Tetradecylammonium Bromide] and the Study of its Thermodynamic Properties," J. Surfactants Deterg, Springer, vol. 13, no. 3, pp. 339-348, 2009.
[7] Bharatiya U. et al., "Effect of Corrosion on Crude Oil and Natural Gas Pipeline with Emphasis on Prevention by Ecofriendly Corrosion Inhibitors: A Comprehensive Review," J. Bio- Tribo-Corrosion, Springer, vol. 5, no. 2, pp. 112, 2019. Doi::10.1007/s40735-019-0225-9
[8] Chernov V.Y, "Influence of Oxygen and Hydrogen Sulfide on the Carbonic-Acid Corrosion of Welded Metal Structures of Oil and Gas Equipment," Mater. Sci., Springer, vol. 37, no. 5, pp. 808-815, 2001.
[9] Ostanov, U. Y., Beknazarov, K. S., & Dzhalilov A.T, "Study by Differential Thermal Analysis and Thermogravimetric Analysis of the Heat Stability of Polyethylene Stabilized with Gossypol Derivatives," J. Int. Polym. Sci. Technol., vol. 38, no. 9, pp. 25-27, 2015. Doi:10.1177/0307174X1504200406
[10] Fouda A.S. et al., "Corrosion Inhibition of Novel Prepared Cationic Surfactants for API N80 Carbon Steel Pipelines in Oil Industries," Surf. Eng. Appl. Electrochem, Springer, vol. 54, no. 2, pp. 180-193, 2018.
[11] Beknazarov K.S. Dzhalilov A.T, "The Synthesis of Oligomeric Derivatives of Gossypol and the Study of Their Antioxidative Properties," Int. Polym. Sci. Technol., vol. 43, no. 3, pp. T25-T30, 2016.
[12] Gonik A.A., "Effect of a Diphilic Corrosion Inhibitor on the Iron Passivity in Oil-Field Electrolytes," Prot. Met. Springer, vol. 41, no. 2, pp. 173-176, 2005.
[13] Matienzo L.J. et al., "Environmental and Adhesive Durability of Aluminium-Polymer Systems Protected with Organic Corrosion Inhibitors," J. Mater. Sci., Springer, vol. 21, no. 5, pp. 1601–1608, 1986.
[14] Wang D. et al., Enhancement Corrosion Resistance of (3methacryloxypropyl) Silsesquioxane Hybrid Films and its Validation by Gas-Molecule Diffusion Coefficients using MD Simulation," J. Sol-Gel Sci. Technol, Springer, vol. 49, no. 3, pp. 293-300, 2008.
[15] Rihan R., Shawabkeh R., Al-Bakr N. "The Effect of Two Amine-Based Corrosion Inhibitors in Improving the Corrosion Resistance of Carbon Steel in Sea Water," J. Mater. Eng. Perform, Springer, vol. 23, no. 3, pp. 693–699, 2014.
[16] Ugryumov O. V. et al., "Corrosion Inhibitors of the Snpkh Brand, 2, The P,N-Containing Corrosion Inhibitor for Protection of OilField Equipment," Prot. Met. Springer, vol. 43, no. 1, pp. 87-94, 2007.
[17] Zhang J. et al., "Theoretical and Experimental Studies for Corrosion Inhibition Performance of Q235 Steel by Imidazoline Inhibitors against CO2 Corrosion," J. Surfactants Deterg, Springer, vol. 16, no. 6, pp. 947-956, 2013.
[18] Askari M. et al., "Downhole Corrosion Inhibitors for Oil and Gas Production – A Review," Appl. Surf. Sci. Adv. Elsevier, vol. 6, pp. 100128, 2021.
[19] Batyeva E.S. et al., "New, Effective Carbon Dioxide and Hydrogen Sulfide Corrosion Inhibitors Based on White Phosphorus, Sulfur, Alcohols, and Amines," Pet. Chem., Springer, vol. 53, no. 2, pp. 139–143, 2013.
[20] Narzullaev, A.X, Beknazarov, X.S, Jalilov, A.T, Rajabova, M.F., "Studying the Efficiency of Corrosion Inhibitor IKTSF-1, IRDEA, IR-DAR-20 in 1m HCl," International Journal of Advanced Science and Technology, vol. 28, no. 15, pp. 113-122, 2019.
[21] Zhang Q.H. et al., "Comparison of the Synergistic Inhibition Mechanism of Two Eco-Friendly Amino Acids Combined Corrosion Inhibitors for Carbon Steel Pipelines in Oil and Gas Production," Appl. Surf. Sci. North-Holland, vol. 583, pp. 152559, 2022. doi: 10.1016/j.apsusc.2022.152559
[22] J.A.A. Yamin, E.Ali Eh Sheet and A. Al-Amiery, "Statistical Analysis and Optimization of the Corrosion Inhibition Efficiency of a Locally Made Corrosion Inhibitor Under Different Operating Variables Using RSM," Int. J. Corros. Scale Inhib., vol. 9, no. 2, pp. 502-518, 2020. doi: 10.17675/2305-6894-2020-9-2-6
[23] Firoz Ahmed, Md. Saifur Rahman, Md. Ibrahim H Mondal, "Cotton Fibre Functionalization With Prepared Carboxymethyl Chitosan From Prawn Shell Waste: An Eco-Friendly Approach," International Journal of Polymer and Textile Engineering, vol. 8, no. 1, pp. 9-14, 2021. Crossref,