Effects of Different Factors on the Kinetics of Modification of Polysilicic Acids with Ethanolamine

Effects of Different Factors on the Kinetics of Modification of Polysilicic Acids with Ethanolamine

  IJETT-book-cover           
  
© 2022 by IJETT Journal
Volume-70 Issue-8
Year of Publication : 2022
Authors : Yusuf Geldiev, Khayit Turaev, Ibragim Umbarov, Khurshid Eshmurodov
DOI : 10.14445/22315381/IJETT-V70I8P245

How to Cite?

Yusuf Geldiev, Khayit Turaev, Ibragim Umbarov, Khurshid Eshmurodov, "Effects of Different Factors on the Kinetics of Modification of Polysilicic Acids with Ethanolamine," International Journal of Engineering Trends and Technology, vol. 70, no. 8, pp. 447-452, 2022. Crossref, https://doi.org/10.14445/22315381/IJETT-V70I8P245

Abstract
The article discusses the effect of various factors on the modification rate of polysilicic acid. The reaction of polysilicic acid with ethanolamine is due to the polycondensation of the silanol and hydroxyl groups. The formation of the corresponding product as a result of the reaction has been confirmed by IR spectroscopy. The dependence of the reaction rate on temperature and the addition of tetraethyl orthosilicate has been studied. The optimum time for modification was shown to be 5 hours without tetraethyl orthosilicate and a temperature of 60°C, and 2 hours and 60°C in the presence of tetraethyl orthosilicate.

Keywords
Silicic acid, Ethanolamine, Tetraethyl orthosilicate, Temperature, Reaction kinetics.

Reference
[1] A. Morikawa et al., Feature article, “Preparation of New Polyimide–Silica Hybrid Materials via the Sol-Gel Process,” J. Mater. Chem. The Royal Society of Chemistry, vol. 2, no. 7, pp. 679–689, 1992.
[2] P.L.Chuang, Y.H.Nien, “Preparation and Characterization of Maleic Anhydride Grafted SEBS/Silica Composites through Modification by Ethanolamine,” Polym. Bull. Springer, vol. 77, no. 5, pp. 2521–2537, 2020.
[3] P.L.Chuang, Y.H.Nien, “Synthesis and Characterization of Maleic Anhydride Grafted SEBS Modified with Ethanolamine, 2-Amino-2- Methyl-1-Propanol or Glycerine,” J. Polym. Res. Springer Netherlands, vol. 26, no. 3, pp. 1-15, 2019.
[4] M. Hayashi et al., “Deactivation of External Acid Sites of H-Mordenite by Silica-Modification in the Isopropylation of Biphenyl,” React. Kinet. Catal. Lett. Vol. 83, no. 2, pp. 329–335, 2004.
[5] S.Y.Onozawa et al., “PEG Modification Effect of Silica on the Suzuki-Miyaura Coupling Reaction using Silica-Immobilized Palladium Catalysts,” Catal. Letters. Kluwer Academic Publishers, vol. 141, no. 6, pp. 866–871, 2011.
[6] Z. Deng et al., “Surface Modification of Silica Aerogels Dried with 2-Methyl-1-Propanol in the Sub-Critical Pressure,” J. Porous Mater, vol. 8, no. 1, pp. 37-42, 2001.
[7] K. Yoshinaga, Y. Tani, Y. Tanaka, “Surface Modification of Fine Colloidal Silica with Copolymer Silane-Coupling Agents Composed of Maleic Anhydride,” Colloid Polym. Sci., vol. 280, no. 1, pp. 85-89, 2002.
[8] Y. Li et al., “A New Surface Modification Method to Improve the Dispersity of Nano-Silica in Organic Solvents,” J. Sol-Gel Sci. Technol, vol. 58, no. 1, pp. 290-295, 2011.
[9] A. Vidal et al., “Modification of Silica Surfaces by Grafting of Alkyl Chains, I — Characterization of Silica Surfaces by Inverse Gas-Solid Chromatography at Zero Surface Coverage,”Chromatogr, vol. 23, no. 2, pp. 121-128, 1987.
[10] L. Li et al., “Modification of Recycled Aggregate by Spraying Colloidal Nano Silica and Silica Fume,” Mater. Struct. Constr., Springer Science and Business Media B.V, vol. 54, no. 6, pp. 1-15, 2021.
[11] Y. Zhang Y. et al., “Adsorption Separation of CO2/CH4 from Landfill Gas by Ethanolamine-Modified Silica Gel,” Water. Air. Soil Pollut. Springer Science and Business Media Deutschland GmbH, vol. 232, no. 2, pp. 1-11, 2021.
[12] D. Chmielewska L, “Stachurska Studies on the Potassium–Nickel Hexacyanoferrate/Ethanolamine/Silica Ion Exchanger for 60Co Removal from Spent Fuel Storage Basins and the Primary Water Circuit of Nuclear Reactors,” J. Radioanal. Nucl. Chem, Springer Netherlands, vol. 307, no. 2, pp. 1295-1301, 2016.
[13] R.A. Khatri et al., “Carbon Dioxide Capture by Diamine-Grafted SBA-15: A Combined Fourier Transform Infrared and Mass Spectrometry Study,” Ind. Eng. Chem Res., vol. 44, no. 10, pp. 3702-3708, 2005.
[14] A. Ghaemi, H. Mashhadimoslem, P. Zohourian Izadpanah, “NiO and MgO/Activated Carbon as an Efficient CO2 Adsorbent: Characterization, Modeling, and Optimization,” Int. J. Environ. Sci. Technol, vol. 19, no. 2, pp. 727-746, 2022.
[15] Ostanov, U.Y., Beknazarov, K.S., Dzhalilov, A.T., “Study by Differential Thermal Analysis and Thermogravimetric Analysis of the Heat Stability of Polyethylene Stabilized with Gossypol Derivatives,” International Polymer Science and Technology, vol. 38, no. 9, pp. 25-27, 2011.
[16] Narzullaev, A.X, Beknazarov, X.S, Jalilov, A.T, Rajabova, M.F., “Studying the Efficiency of Corrosion Inhibitor IKTSF-1, IRDEA, IR-DAR-20 in 1m HCl,” International Journal of Advanced Science and Technology, vol. 28, no. 15, pp. 113-122, 2019.
[17] Beknazarov, K.S., Dzhalilov, A.T., Ostanov, U.Y., Erkaev A.M, “The Inhibition of the Corrosion of Carbon Steel by Oligomeric Corrosion Inhibitors in Different Media,” International Polymer Science and Technology, vol. 42, no. 4, pp. 33-37, 2015.
[18] Cucu E. et al., “Gas Sorption and Selectivity Study of N, N, N′, N′-Tetraphenyl-1,4-Phenylenediamine based Microporous HyperCrosslinked Polymers // Microporous Mesoporous Mater,” Elsevier, vol. 330, pp. 111567, 2022.
[19] R. Sadraei, et al., “Surface Functionalization of Handleable Silica-Based Mesoporous Materials for CO2 Sequestration: Synthesis, Characterization and Performance, Surfaces and Interfaces,” vol. 27, pp. 101542, 2021.
[20] G.G.Kaya H, “Deveci CO2 Capture using Polyethyleneimine Functionalized Silica Xerogels,” Konya J. Eng. Sci. Konya Muhendislik Bilimleri Dergisi, vol. 9, no. 4, pp. 1109–1118 , 2021.
[21] M. Vafaeinia et al., “Oxygen and Nitrogen Enriched Pectin-Derived Micro-Meso Porous Carbon for CO2 Uptake, RSC Adv,” The Royal Society of Chemistry, vol. 12, no. 1, pp. 546-560, 2021.
[22] A. Cherevotan, J. Raj, S.C Peter, “An Overview of Porous Silica Immobilized Amines for Direct Air CO2 Capture,” J. Mater. Chem. A The Royal Society of Chemistry, vol. 9, no. 48, pp. 27271–27303, 2021.
[23] A.M. Santana et al., “Organophosphorus Halloysite Nanotubes as Adsorbent for Lead Preconcentration in Wine and Grape Juice,” Appl. Clay Sci. Elsevier, vol. 200, pp. 105912, 2021.
[24] F. Wang F. et al., “CO2 Adsorption Capacity of Organic Alkali Sorbent CPEI from Polyethyleneimine,” Adsorpt. Sci. Technol. Hindawi Limited, 2021.
[25] C.J. Brinker G.W, “Scherer Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing, Sol-Gel Science,” The Physics and Chemistry of Sol-Gel Processing, vol. 1, pp. 908, 2013.
[26] Kh. Kh. Turaev, D. Kh. Shukurov, A. T. Djalilov and M. U. Karimov, “New Review of Dye Sensitive Solar Cells,” International Journal of Engineering Trends and Technology, vol. 69, no. 9, pp. 265-271, 2021.
[27] Shukurov D.Kh.,Turaev Kh.Kh., Tojiyev P.J., Karimov M.U, “Synthesis of Polyaniline Dye Pigment and Its Study in Dye-Sensitive Solar Cells,” International Journal of Engineering Trends and Technology, vol. 70, no. 4, pp. 236-244, 2022.
[28] H. Hattori et al., “Infrared Study of Silanol Groups on Dealuminated High Silica MFI Zeolite to Correlate Different Types of Silanol Groups with Activity for Conversion of 1-Butene to Propene,” Catal. Letters. Springer, vol. 150, no. 3, pp. 771–780, 2020.
[29] L.Y. Yu, Z.X.Huang, M.X. Shi, “Synthesis and Characterization of Silica by Sol-Gel Method,” Adv. Mater. Res., vol. 1030, pp. 189- 192, 2014.
[30] Michael M. Silaev, "Reaction Kinetics and Kinetic Equations of Free-Radical Nonbranched-Chain Processes of Addition to Unsaturated Compounds," International Journal of Applied Chemistry, vol. 6, no. 3, pp. 62-85, 2019. Crossref, https://doi.org/10.14445/23939133/IJAC-V6I3P110.