Studying of Properties of Bitumen Modified based on Secondary Polymer Wastes Containing Zinc

Studying of Properties of Bitumen Modified based on Secondary Polymer Wastes Containing Zinc

  IJETT-book-cover           
  
© 2023 by IJETT Journal
Volume-71 Issue-9
Year of Publication : 2023
Author : Turayev Kh.Kh., Eshankulov Kh.N., Umbarov I.A., Kasimov Sh.A., Nomozov A.K., Nabiev DA
DOI : 10.14445/22315381/IJETT-V71I9P222

How to Cite?

Turayev Kh.Kh., Eshankulov Kh.N., Umbarov I.A., Kasimov Sh.A., Nomozov A.K., Nabiev DA, "Studying of Properties of Bitumen Modified based on Secondary Polymer Wastes Containing Zinc," International Journal of Engineering Trends and Technology, vol. 71, no. 9, pp. 248-255, 2023. Crossref, https://doi.org/10.14445/22315381/IJETT-V71I9P222

Abstract
This paper uses laboratory experiments to present the properties of zinc-containing secondary polymer (ZnIP) and sulfur-containing modified bitumen. Zinc chloride is used as the main raw material, acrylonitrile as secondary polymer monomers, tri polymers based on isoprene, natural rubber, and styrene. BND 60/90 potential base bitumen is mixed with zinc-preserved secondary polymer (ZnIP) and sulfur in various proportions using a high-shear laboratory-type mixer. The properties and microstructure of the samples determined by conventional and empirical testing methods, IR-spectrum, SEM analysis (Scanning Electron Microscope), elemental analysis, thermal gravimetric (TGA and DTA) analysis, and X-ray phase analysis are studied. The results showed that zinc-containing secondary polymer (ZnIP) and sulfur modification improved the traditional properties of base bitumen, such as a positive change in softening point, temperature sensitivity, etc. The microstructure and properties of zinc-containing secondary polymer (ZnIP) and sulfur-modified bitumen depend on the type of secondary polymer, the solubility of the second polymer in the bitumen, and the composition of the second polymer. The results of the above analysis showed that the physicochemical, viscosity, elasticity, and rheological properties of bitumen modified based on ZnIP-S gave very good results compared to unmodified bitumen. Experiments were conducted proving that bitumen modified based on ZnIP-S increases the elasticity, heat, cracking, and long-term resistance of asphalt.

Keywords
Bitumen, Sulfur-modified bitumen, Acrylonitrile, Isoprene rubber, Styrene, IR-spectrum, Scanning Electron Microscope.

References
[1] Xiang Shu, Baoshan Huang, and Dragon Vukosavljevic, “Laboratory Evaluation of Fatigue Characteristics of Recycled Asphalt Mixture,” Construction and Building Materials, vol. 22, no. 7, pp. 1323-1330, 2008.
[CrossRef] [Google Scholar] [Publisher Link]
[2] Sureyya Tayfur, Halit Ozen, and Atakan Aksoy, “Investigation of Rutting Performance of Asphalt Mixtures Containing Polymer Modifiers,” Construction and Building Materials, vol. 21, no. 2, pp. 328-337, 2007.
[CrossRef] [Google Scholar] [Publisher Link]
[3] Yetkin Yildirim, “Polymer Modified Asphalt Binders,” Construction and Building Materials, vol. 21, no. 1, pp. 66-72, 2007.
[CrossRef] [Google Scholar] [Publisher Link]
[4] Pierre J. Carreau, Mosto Bousmina, and Frank Bonniot, “The Viscoelastic Properties of Polymer-modified Asphalt,” The Canadian Journal of Chemical Engineering, vol. 78, no. 3, pp. 495-503, 2000.
[CrossRef] [Google Scholar] [Publisher Link]
[5] Mahmoud Ameri et al., “Technical Study on the Iranian Gilsonite as an Additive for Modification of Asphalt Binders used in Pavement Construction,” Construction and Building Materials, vol. 25, no. 3, pp. 1379-1387, 2011.
[CrossRef] [Google Scholar] [Publisher Link]
[6] Xiangyoung Li et al., “Evaluation of Ethylene-acrylic Acid Copolymer (EAA) Modified Asphalt: Fundamental Investigations on Mechanical and Rheological Properties,” Construction and Building Materials, vol. 90, pp. 44-52, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[7] Meng Ling et al., “Mechanistic-empirical Models for Top-down Cracking Initiation of Asphalt Pavements,” International Journal of Pavement Engineering, vol. 21, no. 4, pp. 464-473, 2018.
[CrossRef] [Google Scholar] [Publisher Link]
[8] Meng Ling et al., “Enhanced Model for Thermally Induced Transverse Cracking of Asphalt Pavements,” Construction and Building Materials, vol. 206, pp. 130-139, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[9] Gordon D. Airey, “Rheological Properties of Styrene Butadiene Styrene Polymer Modified Road Bitumens,” Fuel, vol. 8/2, no. 14, pp. 1709-1717, 2002.
[CrossRef] [Google Scholar] [Publisher Link]
[10] Gordon D. Airey, Musarrat H. Mohammed, and Caroline Fichter, “Rheological Characteristics of Synthetic Road Binders,” Fuel, vol. 87, no. 10-11, pp. 1763-1775, 2008.
[CrossRef] [Google Scholar] [Publisher Link]
[11] Mohammad Jamal Khattak, and Gilbert Y. Baladi, “Engineering Properties of Polymer-modified Asphalt Mixtures,” Transportation Research Record, vol. 1638, no. 1, pp. 12–22, 1998.
[CrossRef] [Google Scholar] [Publisher Link]
[12] Xiaohu Lu, and Ulf Isacsson, “Laboratory Study on the Low-Temperature Physical Hardening of Conventional and Polymer Modified Bitumens,” Construction and Building Materials, vol. 14, no. 2, pp. 79-88, 2000.
[CrossRef] [Google Scholar] [Publisher Link]
[13] Mahmoud Ameri, and Danial Nasr, “Properties of Asphalt Modified with Devulcanized Polyethylene Terephthalate,” Petroleum Science and Technology, vol. 34, no. 16, pp. 1424-1430, 2016.
[CrossRef] [Google Scholar] [Publisher Link]
[14] Aliyeva Aida, Shixaliyev Karam, and Aliyeva Zahida, “Modification of Bitumen with Polyethylene and Rubber Wastes,” SSRG International Journal of Chemical Engineering Research, vol. 9, no. 2, pp. 13-16, 2022.
[CrossRef] [Publisher Link]
[15] Francesco Canestrari, Lorenzo Paolo Ingrassia, and Amedeo Virgili, “A Semi-Empirical Model for Top-down Cracking Depth Evolution in Thick Asphalt Pavements with Open-graded Friction Courses,” Journal of Traffic and Transportation Engineering, vol. 9, no. 2, pp. 244-260, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[16] Samer Dessouky et al., “Effect of Pre-heating Duration and Temperature Conditioning on the Rheological Properties of Bitumen,” Construction and Building Materials, vol. 25, no. 6, pp. 2785–2792, 2011.
[CrossRef] [Google Scholar] [Publisher Link]
[17] Ali Topal et al., “Evaluation of Rheological and Image Properties of Styrene-butadiene-styrene and Ethylene-vinyl Acetate Polymer Modified Bitumens,” Journal of Applied Polymer Science, vol. 122, no. 5, pp. 3122–3132, 2011.
[CrossRef] [Google Scholar] [Publisher Link]
[18] Dennyele Alves Gama et al., “Rheological Studies of Asphalt Modified with Elastomeric Polymer,” Construction and Building Materials, vol. 106, pp. 290-295, 2016.
[CrossRef] [Google Scholar] [Publisher Link]
[19] Martin Jasso et al., “Rheology of Conventional Asphalt Modified with SBS, Elvaloy and Polyphosphoric Acid,” Fuel Processing Technology, vol. 140, pp. 172-179, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[20] Vineet Dogra, Vinek Rana, and C.B. Mishra, “A Gist of Corollary of Aging on Propensity of Bitumen Containing Polymers,” SSRG International Journal of Civil Engineering, vol. 7, no. 1, pp. 1-4, 2020.
[CrossRef] [Publisher Link]
[21] Giovanni Polacco et al., “A Review of the Fundamentals of Polymer-modified Asphalts: Asphalt/Polymer Interactions and Principles of Compatibility,” Advances in Colloid and Interface Science, vol. 224, pp. 72-112, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[22] Maria de Fátima Amazonas de Sá Araujo et al., “Weathering aging of Modified Asphalt Binders,” Fuel Processing Technology, vol. 115, pp. 19-25, 2013.
[CrossRef] [Google Scholar] [Publisher Link]
[23] Dongdong et al., “Modification Mechanism of Asphalt Modified with Sasobit and Polyphosphoric Acid (PPA),” Construction and Building Materials, vol. 143, pp. 419-428, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[24] Giovanni Polacco et al., “Relation between Polymer Architecture and Nonlinear Viscoelastic Behavior of Modified Asphalts,” Current Opinion in Colloid and Interface Science, vol. 11, no. 4, pp. 230-245, 2006.
[CrossRef] [Google Scholar] [Publisher Link]
[25] Eshankulov Khasan.Nurmuminovich et al., “The Studying Synthesis and Research of Nickel and Tin Acrylate on the Basis of the Copolymers,” Journal of Pharmaceutical Negative Results, vol. 13, no. 7, pp. 3271-3285, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[26] Turaev Khayit, Kholnazarov Bakhodir, and Djalilov Abdulakhad, “Synthesis of Superabsorbent Hydrogels based on Starch-Chitosan Hybrid,” Journal of European Chemical Bulletin, vol. 11, no. 11, pp. 152-161, 2022.
[Google Scholar] [Publisher Link]
[27] Gulnora A. Umirova et al., “Study of Metal Sorption by Covalently Immobilized Polyampholytes based on Amino Acids,” Journal of Chemistry and Chemical Technology, vol. 66, no. 5, pp. 41-51, 2023.
[CrossRef] [Publisher Link]
[28] V. Selvavathi et al., “Modifications of Bitumen by Elastomer and Reactive Polymer-a Comparative Study,” Petroleum Science and Technology, vol. 20, no. 5-6, pp. 535-547, 2002.
[CrossRef] [Google Scholar] [Publisher Link]
[29] Giovanni Polacco et al., “Temporary Networks in Polymer-Modified Asphalts,” Polymer Engineering and Science, vol. 44, no. 12, pp. 2185-2193, 2004.
[CrossRef] [Google Scholar] [Publisher Link]
[30] Ali Topal, “Evaluation of the Properties and Microstructure of Plastomeric Polymer Modified Bitumens,” Fuel Processing Technology, vol. 91, no. 1, pp. 45-51, 2010.
[CrossRef] [Google Scholar] [Publisher Link]
[31] Ch. Naveen Kumar, V. John Prashath, and K. Hari Krishna, “An Experimental Study On Bitumen Properties by Using Medical Plastic Waste,” SSRG International Journal of Civil Engineering, vol. 6, no. 8, pp. 17-29, 2019.
[CrossRef] [Publisher Link]
[32] S. Keyf, “The Modification of Bitumen with Reactive Ethylene Terpolymer, Styrene Butadiene Styrene and Variable Amounts of Ethylene Vinyl Acetate,” Research on Chemical Intermediates, vol. 41, pp. 1485-1497, 2015.
[CrossRef] [Google Scholar] [Publisher Link]