A New Mixed Ligand Copper (II) Complex: Synthesis, Crystal Structure and Hirshfeld Surface Analysis

A New Mixed Ligand Copper (II) Complex: Synthesis, Crystal Structure and Hirshfeld Surface Analysis
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© 2024 by IJETT Journal
Volume-72 Issue-11
Year of Publication : 2024
Author : Toshtemirov A. E, Turaev Kh. Kh, Ibragimov A. B, Umbarov I. A, Ashurov J. M, Alimnazarov B. Kh
DOI : 10.14445/22315381/IJETT-V72I11P114

How to Cite?
Toshtemirov A. E, Turaev Kh. Kh, Ibragimov A. B, Umbarov I. A, Ashurov J. M, Alimnazarov B. Kh, "A New Mixed Ligand Copper (II) Complex: Synthesis, Crystal Structure and Hirshfeld Surface Analysis," International Journal of Engineering Trends and Technology, vol. 72, no. 11, pp. 106-116, 2024. Crossref, https://doi.org/10.14445/22315381/IJETT-V72I11P114

Abstract
In this article, the optimal conditions for synthesizing a new [Cu(phen)(HSO4)2•2H2O] metal complex with the ligand 1,10-phenanthroline and the metal ion Cu (II) were investigated. The obtained complex was analyzed using various physicochemical methods such as X-ray diffraction analysis for determining the molecular structure of the single crystal, elemental analysis, IR spectra, UV-vis, DTA, and TGA. The complex crystallized in a monoclinic form with the P21/n space group. According to the XRD results of the single crystal investigation, it was determined that the Cu (II) complex cation exhibits distorted square-pyramidal geometry with the Jahn-Teller effect in the CuN2O4 core. Additionally, the Hirshfeld surface analysis was studied.

Keywords
Crystal, X-ray, 1,10-fenantrolin, Hirshfeld surface, IR-spectra, UV-vis.

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