Synthesis Hydrogels based on Starch-graftacrylonitrile/bentonite
Synthesis Hydrogels based on Starch-graftacrylonitrile/bentonite |
||
 |
 |
|
| © 2024 by IJETT Journal | ||
| Volume-72 Issue-11 |
||
| Year of Publication : 2024 | ||
| Author : S.M. Samatov, Kh.Kh.Turaev, B.A.Kholnazarov, A.Kh.Toshkulov, D.Kh. Shukurov, A.I. Kholboeva, J.T. Samariddinov, S.T.Abdurakhmonov |
||
| DOI : 10.14445/22315381/IJETT-V72I11P135 | ||
How to Cite?
S.M. Samatov, Kh.Kh.Turaev, B.A.Kholnazarov, A.Kh.Toshkulov, D.Kh. Shukurov, A.I. Kholboeva, J.T. Samariddinov, S.T.Abdurakhmonov, "Synthesis Hydrogels based on Starch-graftacrylonitrile/bentonite," International Journal of Engineering Trends and Technology, vol. 72, no. 11, pp. 371-379, 2024. Crossref, https://doi.org/10.14445/22315381/IJETT-V72I11P135
Abstract
This research aims to obtain low-cost, high-performance agricultural hydrogels with mineral retention based on natural polysaccharide copolymer. It is determined that the swelling properties of hydrogels depend on the concentration of the starting material, the reaction temperature and time of the acidic and alkaline medium, and the concentration of ions in the solution. The obtained hydrogels' water absorption and retention properties were determined in aggressive environments such as salty, acidic and alkaline. The swelling of hydrogels was tested in solutions of salts NaCl, CaCl2 and AlCl3 ions. When starch and bentonite are added to the hydrogel polymer chain and matrix, it was found that its water absorption increased by 25%, water retention time increased by 20%, and water consumption was reduced by 20-25%.
Keywords
Acrylonitrile, High swelling hydrogel, Initiator, Montmorillonite, Saponification, Sodium bicarbonate, Starch.
References
[1] Congming Xiao, “Current Advances of Chemical and Physical Starch-Based Hydrogels,” Starch‐Stärke, vol. 65, no. 1-2, pp. 82-88, 2013.
[CrossRef] [Google Scholar] [Publisher Link]
[2] Hanafi Ismail, Maryam Irani, and Zulkifli Ahmad, “Starch-Based Hydrogels: Present Status and Applications,” International Journal of Polymeric Materials and Polymeric Biomaterials, vol. 62, no. 7, pp. 411-420, 2012.
[CrossRef] [Google Scholar] [Publisher Link]
[3] Lim Sze Lim et al., “Synthesis and Swelling Behavior of pH-Sensitive Semi-IPN Superabsorbent Hydrogels Based on Poly(Acrylic Acid) Reinforced with Cellulose Nanocrystals,” Nanomaterials, vol, 7, no. 11, pp. 1-13, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[4] Pengpeng Chen et al., “Dye Adsorption and Photo-Induced Recycling of Hydroxypropyl Cellulose/Molybdenum-Disulfide Composite Hydrogels,” Carbohydrate Polymers, vol. 167, pp. 36-43, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[5] Ahmed M. Elbarbary et al., “Radiation Induced Crosslinking of Polyacrylamide Incorporated Low Molecular Weights Natural Polymers for Possible Use in Agricultural Applications,” Carbohydrate Polymers, vol. 176, pp. 19-28, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[6] Magdalena Zdanowicz, Beata Schmidt, and Tadeusz Spychaj, “Starch Graft Copolymers as Superabsorbents Obtained Via Reactive Extrusion Processing,” Polish Journal of Chemical Technology, vol. 12, no. 2, pp. 14-17, 2010.
[CrossRef] [Google Scholar] [Publisher Link]
[7] Hatika Kaco et al., “Properties of Cellulose Hydrogel From Kenaf Core Prepared Via Pre-Cooled Dissolving Method,” Sains Malaysiana, vol. 43, no. 8, pp. 1221-1229, 2014.
[Google Scholar] [Publisher Link]
[8] Rui Liang et al., “Synthesis of Wheat Straw-G-Poly (Acrylic Acid) Superabsorbent Composites and Release of Urea From It,” Carbohydrate Polymers, vol. 77, no. 2, pp. 181-187, 2009.
[CrossRef] [Google Scholar] [Publisher Link]
[9] Kang Zhong et al., “Starch Derivative-Based Superabsorbent with Integration of Water-Retaining and Controlled-Release Fertilizers,” Carbohydrate Polymers, vol. 92, no. 2, pp. 1367-1376, 2013.
[CrossRef] [Google Scholar] [Publisher Link]
[10] Toshio Yoshimura et al., “Synthesis and Characterization of Biodegradable Hydrogels Based on Starch and Succinicanhydride,” Carbohydrate Polymers, vol. 64, no. 2, pp. 345-349, 2006.
[CrossRef] [Google Scholar] [Publisher Link]
[11] Cristiane Spagnol et al., “Superabsorbent Hydrogel Nanocomposites Based on Starch-G-Poly (Sodium Acrylate) Matrix Filled with Cellulose Nanowhiskers,” Cellulose, vol. 19, pp. 1225-1235, 2012.
[CrossRef] [Google Scholar] [Publisher Link]
[12] Ortal Yom-Tov, Dror Seliktar, and Havazelet Bianco-Peled, “PEG-Thiol Based Hydrogels with Controllable Properties,” European Polymer Journal, vol. 74, pp. 1-12, 2016.
[CrossRef] [Google Scholar] [Publisher Link]
[13] Najiyyah Abdullah Sirajuddin, Mohd Suzeren Md Jamil, and Muhammad Azwani Shah Mat Lazim, “Effect of Crosslink Density and the Healing Efficiency of Self-Healing Poly (2-Hydroxymethyl Methacrylate) Hydrogel,” E-Polymers, vol. 14, no. 4, pp. 289-294, 2014.
[CrossRef] [Google Scholar] [Publisher Link]
[14] A. Hajighasem, and K. Kabiri, “Cationic Highly-Alcohol Swellable Gels: Synthesis and Characterization,” Journal of Polymer Research, vol. 20, 2013.
[CrossRef] [Google Scholar] [Publisher Link]
[15] Hongjie Dai et al., “Pineapple Peel Carboxymethyl Cellulose/Polyvinyl Alcohol/Mesoporous Silica Sba-15 Hydrogel Composites for Papain Immobilization,” Carbohydrate Polymers, vol. 169, pp. 504-514, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[16] Tayeb Benhalima, Hafida Ferfera-Harrar, and Djahida Lerari, “Optimization of Carboxymethyl Cellulose Hydrogels Beads Generated by Anionic Surfactant Micelle Templating for Cationic Dye Uptake: Swelling, Sorption, and Reusability Studies,” International Journal of Biological Macromolecules, vol. 105, no. 1, pp. 1025-1042, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[17] Narendra Reddy, Roopa Reddy, and Qiuran Jiang, “Crosslinking Biopolymers for Biomedical Applications,” Trends Biotechnology, vol. 33, no. 6, pp. 362-369, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[18] Bidyadhar Mandal, and Samit Kumar Ray, “Removal of Safranine T And Brilliant Cresyl Blue Dyes from Water by Carboxymethyl Cellulose Incorporated Acrylic Hydrogel: Isotherms, Kinetics and Thermodynamic Study,” Journal of the Taiwan Institute of Chemical Engineers, vol. 18, pp. 1-15, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[19] Dongbei Wu et al., “Gum Arabic: A Promising Candidate for the Construction of Physical Hydrogel Exhibiting Highly Stretchable, Self-Healing and Tensility Reinforcing Performance,” Carbohydrate Polymers, vol. 181, pp. 167-174, 2018.
[CrossRef] [Google Scholar] [Publisher Link]
[20] Tran Thu Hong et al., “Removal of Metal Ions From Aqueous Solutions Using Carboxymethyl Cellulose/Sodium Styrene Sulfonate Gels Prepared by Radiation Grafting,” Carbohydrate Polymers, vol. 157, pp. 335-343, 2016.
[CrossRef] [Google Scholar] [Publisher Link]
[21] Maznah Mahmud, Rusli Daik, and Zainah Adam, “Influence of Poly(Ethylene Glycol) on the Characteristics of γ Radiation-Crosslinked Poly(Vinyl Pyrrolidone)-Low Molecular Weight Chitosan Network Hydrogels,” Sains Malaysiana, vol. 47, no. 6, pp. 1189-1197, 2018.
[CrossRef] [Google Scholar] [Publisher Link]
[22] Oana Cadar et al., “Biodegradation of Poly(Lactic Acid) and (Lactic Acid-Ethylene-Malonic or Succinic Acid) Copolymers Under Controlled Composting Conditions in a Laboratory System,” Polymer Degradation and Stability, vol. 97, no. 3, pp. 354-357, 2012.
[CrossRef] [Google Scholar] [Publisher Link]