IJBTT

Synthesis of the Complex Compounds of Zn (II) and Co (II) with Isoniazid (Pyridine-4-Carbohydrazide)

Synthesis of the Complex Compounds of Zn (II) and Co (II) with Isoniazid (Pyridine-4-Carbohydrazide)
	© 2024 by IJETT Journal
	Volume-72 Issue-8
	Year of Publication : 2024
	Author : Muratov B.A, Turaev Kh.Kh, Umbarov I.A, Kasimov Sh.A, Allaberdiyev F.H, Alimnazarov,B.Kh
	DOI : 10.14445/22315381/IJETT-V72I8P124

How to Cite?

Muratov B.A, Turaev Kh.Kh, Umbarov I.A, Kasimov Sh.A, Allaberdiyev F.H, Alimnazarov,B.Kh,"Synthesis of the Complex Compounds of Zn (II) and Co (II) with Isoniazid (Pyridine-4-Carbohydrazide)," International Journal of Engineering Trends and Technology, vol. 72, no. 8, pp. 244-252, 2024. Crossref, https://doi.org/10.14445/22315381/IJETT-V72I8P124

Abstract
In this paper, the optimal conditions for the complexation of isoniazid (pyridine-4-carbohydrazide) with some 3d-metal Zn (NO3)2 and Co (NO3)2 salts were studied. In this case, complex compounds [Zn(L)2] and [Co(L)2] were synthesized in a 2:1 ratio of Ligand and Metal and a weakly acidic pH=5 environment. The composition and structure of the synthesized complex were studied using modern physico-chemical methods. In particular, the structure of the obtained compound was studied using IR-Fourier spectroscopy, mass spectrometry and elemental analysis methods, and the chemical structure of complex compounds was determined. According to the results of TGA and DTA analysis, it was confirmed that the synthesized complex compounds containing [Me(L)2] are stable and specific to the ligand.

Keywords
Isoniazid, Zinc nitrate, Cobalt nitrate, Ethanol, Chromatomass spectrum, Scanning electron microscope, IR spectrum.

References
[1] Matthew N. Hopkinson et al., “An Overview of N-heterocyclic Carbenes,” Nature, vol. 510, pp. 485–496, 2014.
[CrossRef] [Google Scholar] [Publisher Link]
[2] Yetkin Gök et al., “2-Methyl-1,4-Benzodioxan-Substituted Bis(NHC)PdX2 Complexes: Synthesis, Characterization and the Catalytic Activity in the Direct Arylation Reaction of Some 2-Alkyl-Heterocyclic Compounds,” Journal of the Iranian Chemical Society, vol. 16, pp. 423–433, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[3] S.V. Larionov et al., “Synthesis, Structure, and Properties of Nickel(II) and Cobalt(II) Coordination Compounds with Optically Active Diaminodioxime (H2L) Derived from 3-Carene. Molecular and Crystal Structures of the [Ni(H2L)(NO3)]NO3 and [Ni(HL)]ClO4 • H2O Complexes,” Russian Journal of Coordination Chemistry, vol. 29, pp. 795–804, 2003.
[CrossRef] [Google Scholar] [Publisher Link]
[4] V.S. Sergienko et al., “Synthesis and Structure of Dioxomolibdenum(VI) Complexes with Hydrazones of β-Dicarbonyl Compounds. Crystal Structures of Benzoylacetone Nicotinoylhydrazone (H2L1), Acetoacetanilide Benzoylhydrazone (H2L2), and MoO2L1•MeOH Solvate,” Russian Journal of General Chemistry, vol. 92, pp. 1032–1039, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[5] A.V. Parsalova et al., “Coordination Compounds of Certain of Lanthanoides with 2-Furancarboxylic and 2-Furylacrylic Acids. Synthesis, Structure, and Photoluminescent Properties,” Russian Journal of General Chemistry, vol. 92, pp. 2478–2485, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[6] V.S. Sergienko et al., “Synthesis and Structures of Dioxomolybdenum(VI) Complexes with Hydrazones of β-Dicarbonic Compounds. Crystal Structures of Solvate Complexes МоО2L1⋅МеОН (H2L1 = Isonicotinoylhydrazone Acetylacetone) and МоО2L2 ⋅Me2SO (H2L2 = Benzoylhydrazone Benzoylacetone),” Russian Journal of Inorganic Chemistry, vol. 66, pp. 1854–1859, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[7] A.S. Burlov et al., “Chemical and Electrochemical Synthesis, Local Atomic Structure, and Properties of Copper(II), Cobalt(II), and Nickel(II) Complexes with azo Compounds Containing an Additional azo group in the Para or Ortho Position of the Amine Fragment,” Russian Journal of General Chemistry, vol. 85, pp. 2338–2347, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[8] E.V. Lider et al., “Coordination Compounds of Cobalt(II), Nickel(II), and Copper(II) with 4-(3-Hydroxyphenyl)-1,2,4-Triazole: Synthesis and Study,” Russian Journal of Coordination Chemistry, vol. 36, pp. 337–346, 2010.
[CrossRef] [Google Scholar] [Publisher Link]
[9] A.P. Gulea et al., “Synthesis, Structure, and Biological Activity of Copper(II), Nickel(II), Cobalt(III), and Iron(III) Coordination Compounds with 2-{2-[(Prop-2-en-1-yl)Carbamothioyl]Hydrazinylidene}Propanoic Acid,” Russian Journal of General Chemistry, vol. 90, pp. 2120–2127, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[10] Khayit Turaev et al., “Application of Sulfur-2,4-dinitrophenylhydrazine as Modifier for Producing an Advantageous Concrete,” Baghdad Science Journal, vol. 20, no. 6, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[11] Berta Barta Holló et al., “Synthesis, Physicochemical, and Thermal Characterization of Coordination Compounds of Cu(II) with a Pyrazole-Type Ligand,” Journal of Thermal Analysis and Calorimetry, vol. 142, pp. 451–460, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[12] Nomozov Abror Karim Ugli et al., “Salsola Oppositifolia Acid Extract as a Green Corrosion Inhibitor for Carbon Steel,” Indian Journal of Chemical Technology, vol. 30, no. 6, pp. 872-877, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[13] A.P. Gulea et al., “Synthesis, Structure and Biological Activity of Coordination Compounds of Copper, Nickel, Cobalt, and Iron with Ethyl N'-(2-Hydroxybenzylidene)-N-Prop-2-en-1-Ylcarbamohydrazonothioate,” Russian Journal of General Chemistry, vol. 90, pp. 630–639, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[14] M.A. Shaymardanova et al., “Study of Process of Obtaining Monopotassium Phosphate Based on Monosodium Phosphate and Potassium Chloride,” Chemical Problems, vol. 3, no. 21, pp. 279-293, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[15] A.V. Ermolaev, A.I. Smolentsev, and Yu. V. Mironov, “Hydrothermal Synthesis and Study of Compounds Based on Copper(I) Cyanide and Octahedral Rhenium CyanoHydroxo Cluster Complexes,” Russian Journal of Coordination Chemistry, vol. 47, pp. 473–479, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[16] Yu. V. Kokunov et al., “Coordination Compounds of Cobalt(II) and Cadmium(II) with 2-Amino-4-Methylpyrimidine: Synthesis, Crystal Structure, and Luminescent Properties,” Russian Journal of Inorganic Chemistry, vol. 58, pp. 1187–1192, 2013.
[CrossRef] [Google Scholar] [Publisher Link]
[17] L.G. Lavrenova et al., “Synthesis and Properties of Iron(II) and Copper(II) Coordination Compounds with 2,6-Bis[1-(phenylimino)ethyl]pyridine,” Russian Journal of General Chemistry, vol. 91, pp. 2167–2175, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[18] N.N. Bukov, L.I. Ivashchenko, and V.T. Panyushkin, “Coordination Compounds of Lanthanides with 3-Hydroxy-4-oxo-4H-Pyran-2,6-Dicarboxylic Acid: Synthesis, Structure, and Photoluminescent Properties,” Russian Journal of General Chemistry, vol. 91, pp. 678–684, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[19] V.S. Sergienko et al., “Synthesis and Characterization of Coordination Compounds of 3d-Metal Malonates with Phenylacetyl Hydrazide. Crystal Structure of [Cu(L)2][Cu(Mal)2] • 4.5H2O (L Is Phenylacetyl Hydrazide, Mal2– Is Malonic Acid Anion),” Russian Journal of Coordination Chemistry, vol. 45, pp. 97–104, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[20] A.P. Gulea et al., “Synthesis, Structure, and Biological Activity of Mixed-Ligand Amine-Containing Copper(II) Coordination Compounds with 2-(2-Hydroxybenzylidene)-N-(Prop-2-en-1-yl)Hydrazinecarbothioamide,” Russian Journal of General Chemistry, vol. 91, pp. 98–107, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[21] A.V. Pulya et al., “Synthesis and Characterization of Mn(II) Coordination Compounds with 2-(7-Bromo-2-Oxo-5-Phenyl-3H-1,4-Benzdiazepin-1-yl)Cetohydrazide and its Condensation Product with Pyruvic Acid,” Russian Journal of Inorganic Chemistry, vol. 60, pp. 51–54, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[22] A.P. Gulea et al., “Synthesis, Structure, and Biological Activity of Coordination Compounds of Cobalt(II), Nickel(II), and Copper(II) with N-(Methoxyphenyl)-2-[(5-Nitrofuryl)Methylene]Hydrazine Carbothioamides,” Russian Journal of General Chemistry, vol. 89, pp. 1415–1423, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[23] I.V. Kalinina et al., “Cluster Cyanide-Bridged Heterometallic Coordination Polymers: Synthesis and Crystal Structures of Compounds [{Cu2(dien)2(CN)}2{Mo4Te4(CN)12}]•14.5H2O and (H3O)3K[{Mn(H2O)2}2{Mn(H2O)2(NO3)}4{W4Te4(CN)12}2]•8H2O,” Russian Chemical Bulletin, vol. 53, pp. 2135–2141, 2004.
[CrossRef] [Google Scholar] [Publisher Link]
[24] Z.A. Savelyeva et al., “Synthesis and Structure of Binuclear Compounds of Copper(I) with [(3,5-Dimethylpyrazole-1-Carbothioyl)-Amino]-Carboxylic Esters,” Journal of Structural Chemistry, vol. 46, pp. 122–130, 2005.
[CrossRef] [Google Scholar] [Publisher Link]
[25] Benita Barton, Daniel V. Jooste, and Eric C. Hosten, “Synthesis and Assessment of Compounds Trans-N,N′-Bis(9-Phenyl-9-Xanthenyl)Cyclohexane-1,4-Diamine and Trans-N,N′-Bis(9-Phenyl-9-Thioxanthenyl)Cyclohexane-1,4-Diamine as Hosts for Potential Xylene and Ethylbenzene Guests,” Journal of Inclusion Phenomena and Macrocyclic Chemistry, vol. 93, pp. 333–346, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[26] M. Montazerozohori, “Synthesis, Spectroscopic, and Thermal Studies of Some Hg(II) and Cd(II) Coordination Compounds of N,N-Bis[(E)-3-(Phenylprop)-2-Enylidene]Propanediamine,” Journal of Thermal Analysis and Calorimetry, vol. 111, pp. 121–128, 2013.
[CrossRef] [Google Scholar] [Publisher Link]
[27] Sh. S. Nazirov et al., “Spectrophotometric Determination Of Copper(II) Ion with 7-Bromo-2-Nitroso-1-Oxinaphthalene-3,6-Disulphocid,” Indian Journal of Chemistry-(IJC), vol. 63, no. 5, pp. 500-505, 2024.
[CrossRef] [Google Scholar] [Publisher Link]
[28] A.P. Gulea et al., “Synthesis, Structure, and Biological Activity of Copper and Cobalt Coordination Compounds with Substituted 2-(2-Hydroxybenzylidene)-N-(Prop-2-en-1-yl)Hydrazinecarbothioamides,” Russian Journal of General Chemistry, vol. 89, pp. 953–964, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[29] Yulchieva Marguba Gafurjanovna et al., “Studying Synthesis of a Chelate-Forming Sorbent Based on Urea-Formaldehyde and Diphenylcarbazone,” Indian Journal of Chemistry-(IJC), vol. 63, no. 6, pp. 579-585, 2024.
[CrossRef] [Google Scholar] [Publisher Link]