Preparation of Hydrogel based on Starch, Carboxymethyl Cellulose, Methylene-bis-acralamide and its Application

Preparation of Hydrogel based on Starch, Carboxymethyl Cellulose, Methylene-bis-acralamide and its Application
  IJETT-book-cover           
  
© 2024 by IJETT Journal
Volume-72 Issue-9
Year of Publication : 2024
Author : Kulmatov K.A, Turaev Kh.Kh, Kholnazarov B.A, Shukurov D.Kh
DOI : 10.14445/22315381/IJETT-V72I9P119

How to Cite?
Kulmatov K.A, Turaev Kh.Kh, Kholnazarov B.A, Shukurov D.Kh, "Preparation of Hydrogel based on Starch, Carboxymethyl Cellulose, Methylene-bis-acralamide and its Application," International Journal of Engineering Trends and Technology, vol. 72, no. 9, pp. 241-251, 2024. Crossref, https://doi.org/10.14445/22315381/IJETT-V72I9P119

Abstract
The article provides information about starch, carboxyl methyl cellulose, methylene bis-acralamide, and the technology of making highly elastic hydrogel based on them and their application. Brief information on the level of research on hydrogels is given using the literature. The synthesis process of the hydrogel, the amount of starch, and carboxyl methylcellulose were studied on the basis of percentages, and the swelling of the hydrogel was expressed in mg, and the water absorption was expressed in ml. IR spectrum, thermal analysis, thermogravimetry, Roman spectrum, and SEM analysis of hydrogel were obtained and analyzed. Simply put, 10 grams of the hydrogel can hold up to 2.5-4 liters of water. When used correctly, the hydrogel can save 20-40 percent of irrigation water for most agricultural crops. Finally, the importance of hydrogel in agricultural plants is summarized.

Keywords
Acrylamide, Acrylic acid, KMS, Montmorillonite, Superabsorbent hydrogel.

References

[1] M.A. Askarov, and I.I. Ismailov, Chemistry and Physics of Polymers, 2004.
[Publisher Link]
[2] Andrzej G. Chmielewski, Mohammad Haji-Saeid, and Shamshad Ahmed, “Progress in Radiation Processing of Polymers,” Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, vol. 236, no. 1-4, pp. 44-54, 2005.
[CrossRef] [Google Scholar] [Publisher Link]
[3] Xiaopeng Xiong, Lina Zhang, and Yifeng Wang, “Polymer Fractionation Using Chromatographic Column Packed With Novel Regenerated Cellulose Beads Modified With Silane,” Journal of Chromatography A, vol. 1063, no. 1-2, pp. 71-77, 2005.
[CrossRef] [Google Scholar] [Publisher Link]
[4] M.J. Zohuriaan-Mehr et al., “Advances in Non-Hygienic Applications of Superabsorbent Hydrogel Materials,” Journal of Materials Science, vol. 45, pp. 5711-5735, 2010.
[CrossRef] [Google Scholar] [Publisher Link]
[5] Waham Ashaier Laftah, Shahrir Hashim, and Akos N. Ibrahim “Polymer Hydrogels: A Review,” Polymer-Plastics Technology and Engineering, vol. 50, no. 14, pp. 1475-1486, 2011.
[CrossRef] [Google Scholar] [Publisher Link]
[6] Elżbieta Czarnecka, and Jacek Nowaczyk, “Semi-Natural Superabsorbents Based on Starch-g-Poly (Acrylic Acid): Modification, Synthesis and Application,” Polymers, vol. 12, no. 8, pp. 1-19, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[7] Bakhodir Kholnazarov, Khayit Turaev, and Abdulakhad Djalilov, “Synthesis of Superabsorbent Hydrogels Based on Starch Copolymer/Minerals Powder,” International Journal of Engineering Trends and Technology, vol. 70, no. 12, pp. 351-358, 2022.
[Google Scholar] [Publisher Link]
[8] Khadiga Alharbi et al., “Controlled Release of Phosphorous Fertilizer Bound to Carboxymethyl Starch-G-Polyacrylamide and Maintaining a Hydration Level for the Plant,” International Journal of Biological Macromolecules, vol. 116, pp. 224-231, 2018.
[CrossRef] [Google Scholar] [Publisher Link]
[9] V. Singh et al., “Peroxydisulfate Initiated Synthesis of Potato Starch-Graft-Poly (Acrylonitrile) Under Microwave Irradiation,” Express Polymer Letters, vol. 1, no. 1, pp. 51-58, 2007.
[CrossRef] [Google Scholar] [Publisher Link]
[10] El-Refaie Kenawy et al., “Physically Crosslinked Poly(Vinyl Alcohol)-Hydroxyethyl Starch Blend Hydrogel Membranes: Synthesis And Characterization For Biomedical Applications,” Arabian Journal of Chemistry, vol. 7, no. 3, pp. 372-380, 2014.
[CrossRef] [Google Scholar] [Publisher Link]
[11] Iman Dankar et al., “Characterization of Food Additive-Potato Starch by FTIR and X-Ray Diffraction,” Food Chemistry, vol. 260, pp. 7-12. 2018.
[CrossRef] [Google Scholar] [Publisher Link]
[12] Hany El-Hamshary et al., “Synthesis and Antibacterial of Carboxymethyl Starch-Grafted Poly (Vinyl Imidazole) against Some Plant Pathogens,” International Journal of Biological Macromolecules, vol. 72, pp. 1466-1472, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[13] Thomas Heinze, and Andreas Koschella, “Carboxylmethyl Ethers of Cellulose and Starch - A Review,” Macromolecular Symposia, vol. 223, no. 1, pp. 13-40, 2005.
[CrossRef] [Google Scholar] [Publisher Link]
[14] C.W. Hoogendam et al., “Persistence Length of Carboxymethyl Cellulose as Evaluated From Size Exclusion Chromatography and Potentiometric Titrations,” Macromolecules, vol. 31, no. 18, pp. 6297-6309, 1998.
[CrossRef] [Google Scholar] [Publisher Link]
[15] C. Vinatier et al., “An Injectable Cellulose-Based Hydrogel for Transfer of Autologous Nasal Chondrocytes in Articular Cartilage Defects,” Biotechnology and Bioengineering, vol. 102, no. 4, pp.1259-1267, 2009.
[CrossRef] [Google Scholar] [Publisher Link]
[16] Chunyu Chang et al., “Superabsorbent Hydrogels Based on Cellulose for Smart Swelling and Controllable Delivery,” European Polymer Journal, vol. 46, no. 1, pp. 92-100, 2010.
[CrossRef] [Google Scholar] [Publisher Link]
[17] Sang Ho Ye et al., “Antifouling Blood Purification Membrane Composed of Cellulose Acetate and Phospholipid Polymer,” Biomaterials, vol. 24, no. 23, pp. 4143-4152, 2003.
[CrossRef] [Google Scholar] [Publisher Link]
[18] A. Sannino et al., “Spin Coating Cellulose Derivatives on Quartz Crystal Microbalance Plates to Obtain Hydrogelbased Fast Sensors and Actuators,” Journal of Applied Polymer Science, vol. 106, no. 5, pp. 3040-3050, 2007.
[CrossRef] [Google Scholar] [Publisher Link]
[19] C. Ivanov et al., “Synthesis of Poly(Vinylalcohol)- Methyl Cellulose Hydrogel as Possible Scaffolds in Tissue Engineering,” Journal of Optoelectronics and Advanced Materials, vol. 9, pp. 344-3444, 2007.
[Google Scholar]
[20] Dao Zhou, Lina Zhang, and Shenglian Guo, “Mechanism of Lead Biosorption on Cellulose/Chitin Beads,” Water Research, vol. 39, no. 16, pp. 3755-3762, 2005.
[CrossRef] [Google Scholar] [Publisher Link]
[21] Istvan Siro, and David Plackett, “Microfibrillated Cellulose and New Nanocomposite Materials: A Review,” Cellulose, vol. 17, pp. 459-494, 2010.
[CrossRef] [Google Scholar] [Publisher Link]
[22] V.D. Athawale, and Vidyagauri Lele, “Graft Copolymerization onto Starch. II. Grafting of Acrylic Acid and Preparation of Ithydrogels,” Carbohydrate Polymers, vol. 35, no. 1-2, pp. 21-27, 1998.
[CrossRef] [Google Scholar] [Publisher Link]