Polymer Composites Reinforced with Cellulosic and Cellulosic-Synthetic Fillers: A Numerical and Experimental Study

Polymer Composites Reinforced with Cellulosic and Cellulosic-Synthetic Fillers: A Numerical and Experimental Study

  IJETT-book-cover           
  
© 2025 by IJETT Journal
Volume-73 Issue-1
Year of Publication : 2025
Author : Wilson Webo, Moshibudi Caroline Khoathane, Washington Mhike
DOI : 10.14445/22315381/IJETT-V73I1P101

How to Cite?
Wilson Webo, Moshibudi Caroline Khoathane, Washington Mhike, "Polymer Composites Reinforced with Cellulosic and Cellulosic-Synthetic Fillers: A Numerical and Experimental Study," International Journal of Engineering Trends and Technology, vol. 73, no. 1, pp. 1-13, 2025. Crossref, https://doi.org/10.14445/22315381/IJETT-V73I1P101

Abstract
The increasing generation of wood waste presents an opportunity for sustainable material development. This study investigates the properties of polypropylene (PP) composites reinforced with wood powder and a hybrid of wood and glass powder fillers. The filler contents of the composites ranged from 0% to 50%. Tensile strength decreased with increasing wood powder content, where neat PP exhibited a tensile strength of 34.24 MPa, dropping to 29.55 MPa with 10% wood powder and 20.32 MPa at 50%. However, the hybrid composites improved performance, with tensile strength peaking at 33.50 MPa at 10% hybrid filler content. Thermogravimetric analysis revealed higher thermal stability in hybrid composites, with degradation onset at 300ºC, compared to 350ºC for neat PP. Scanning electron microscopy showed weak interfacial bonding in wood powder composites but better bonding in hybrid composites, enhancing performance. The study demonstrates the potential of hybrid fillers for applications where enhanced thermal stability and moderate mechanical strength are acceptable.

Keywords
Experimental, Glass powder, Polypropylene, Polymer, Numerical, Wood powder, Tensile.

References

[1] Hans Raj et al., “Green Composites Using Naturally Occurring Fibers: A Comprehensive Review,” Sustainable Polyner and Energy, vol. 1, no. 2, pp. 1-26, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[2] S. Demirdag, “The Effect of Using Different Polymer and Cement Based Materials in Pore Filling Applications on Technical Parameters of Travertine Stone,” Construction and Building Materials, vol. 23, no. 1, pp. 522-530, 2009.
[CrossRef] [Google Scholar] [Publisher Link]
[3] Hui Wei et al., “Towards Strong and Stiff Carbon Nanotube-Reinforced High-Strength Aluminum Alloy Composites Through a Microlaminated Architecture Design,” Scripta Materialia, vol. 75, pp. 30-33, 2014.
[CrossRef] [Google Scholar] [Publisher Link]
[4] Filipe V. Ferreira et al., “An Overview on Properties and Applications of Poly (Butylene Adipate-Co-Terephthalate) - PBAT Based Composites,” Polymer Science and Engineering, vol. 59, no. s2, pp. E7-E15, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[5] Y. Sahin, “Preparation and Some Properties of SiC Particle Reinforced Aluminium Alloy Composites,” Materials and Design, vol. 24, no. 8, pp. 671-679, 2003.
[CrossRef] [Google Scholar] [Publisher Link]
[6] Rapheal Ogabi et al., “A Study of Thermal Degradation and Fire Behaviour of Polymer Composites and Their Gaseous Emission Assessment,” Energies, vol. 14, no. 21, pp. 671-679, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[7] Thiago F. Santos et al., “Towards Sustainable and Ecofriendly Polymer Composite Materials from Bast Fibers: A Systematic Review,” Engineering Research Express, vol. 6, pp. 1-26, 2024.
[CrossRef] [Google Scholar] [Publisher Link]
[8] Hossein Abdollahiparsa et al., “A Review of Recent Developments in Structural Applications of Natural Fiber-Reinforced Composites (NFRCs),” Composites and Advanced Materials, vol. 32, pp. 1-18, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[9] Biao Chen et al., “Load Transfer Strengthening in Carbon Nanotubes Reinforced Metal Matrix Composites Via In-Situ Tensile Tests,” Composites Science and Technology, vol. 113, pp. 1-8, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[10] Sivasubramanian Palanisamy et al., “The Prospects of Natural Fiber Composites: A Brief Review,” International-Journal-of-Lightweight Materials-and-Manufacture, vol. 7, no. 4, pp. 496-506, 2024.
[CrossRef] [Google Scholar] [Publisher Link]
[11] Noor K. Faheed, Qahtan A. Hamad, and Rasha Abdul-Hassan Issa, “Investigation of the Effect of Thermal, Mechanical, and Morphological Properties of Bio-Composites Prosthetic Socket,” Composite Interfaces, vol. 31, no. 3, pp. 331-355, 2024.
[CrossRef] [Google Scholar] [Publisher Link]
[12] Mariana D. Banea, and Sandip Budhe, Water Sorption and Solvent Sorption Techniques of Epoxy/Synthetic/Natural Fiber Composites, Handbook of Epoxy/Fiber Composites, Springer, Singapore, pp. 999-1028, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[13] Kazuya Okubo, Toru Fujii, and Erik T. Thostenson, “Multi-Scale Hybrid Biocomposite: Processing and Mechanical Characterization of Bamboo Fiber Reinforced PLA with Microfibrillated Cellulose,” Composites Part A: Applied Science and Manufacturing, vol. 40, no. 4, pp. 469-475, 2009.
[CrossRef] [Google Scholar] [Publisher Link]
[14] D.D. Siqueira et al., “Tailored PCL/Macaíba Fiber to Reach Sustainable Biocomposites,” Journal of Materials Research and Technology, vol. 9, no. 5, pp. 9691-9708, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[15] Benjamin Bax, and Jörg Müssig, “Impact and Tensile Properties of PLA/Cordenka and PLA/flax Composites,” Composites Science and Technology, vol. 68, no. 7-8, pp. 1601-1607, 2008.
[CrossRef] [Google Scholar] [Publisher Link]
[16] M.S. Huda et al., “Green” Composites from Recycled Cellulose and Poly (Lactic Acid): Physico-Mechanical and Morphological Properties Evaluation,” Journal of Materials Science, vol. 40, pp. 4221-4229, 2005.
[CrossRef] [Google Scholar] [Publisher Link]
[17] Kristiina Oksman et al., “Review of the Recent Developments in Cellulose Nanocomposite Processing,” Composites Part A: Applied Science and Manufacturing, vol. 83, pp. 2-18, 2016.
[CrossRef] [Google Scholar] [Publisher Link]
[18] Zita Dominkovics, Lívia Danyadi, and Béla Pukanszky, “Surface Modification of Wood Flour and Its Effect on The Properties of PP/wood Composites, Composites Part A: Applied Science and Manufacturing, vol. 38, no. 8, pp. 1893-1901, 2007.
[CrossRef] [Google Scholar] [Publisher Link]
[19] A. Sudár et al., “The Mechanism and Kinetics of Void Formation and Growth in Particulate Filled PE Composites,” Express Polymer Letters, vol. 1, no. 11, pp. 763-772, 2007.
[Google Scholar] [Publisher Link]
[20] Md Mominul Haque et al., “Chemical Treatment of Coir Fiber Reinforced Polypropylene Composites,” Industrial and Engineering Chemistry Research, vol. 51, no. 10, pp. 3958-3965, 2012.
[CrossRef] [Google Scholar] [Publisher Link]
[21] Md Minhaz-Ul Haque, “Fatigue Analysis and Failure Reliability of Polypropylene/Wood Flour Composites,” Advanced Industrial and Engineering Polymer Research, vol. 2, no. 3, pp. 136-142, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[22] Róbert Várdai et al., “Improvement of the Impact Resistance of Natural Fiber–Reinforced Polypropylene Composites Through Hybridization,” Polymers Advanced Technologies, vol. 32, no. 6, pp. 2499-2507, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[23] Zhangzhang Tang et al., “3D Printing of a Versatile Applicability Shape Memory Polymer with High Strength and High Transition Temperature,” Chemical Engineering Journal, vol. 431, no. 2, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[24] Wen Wang et al., “Flexible Supercapacitors Based on Stretchable Conducting Polymer Electrodes,” Polymers, vol. 15, no. 8, pp. 1-12, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[25] Gaurav Madhu et al., “Physico-Mechanical Properties and Biodegradation of Oxo-Degradable HDPE/PLA Blends,” Polymer Science Series A, vol. 58, pp. 57-75, 2016.
[CrossRef] [Google Scholar] [Publisher Link]
[26] Nicole E. Zander et al., “Recycled Polypropylene Blends as Novel 3D Printing Materials,” Additive Manufacturing, vol. 25, pp. 122-130, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[27] Sujit S. Pawar et al., “Carbon Fiber Sizing Agents Based on Renewable Terpenes,” Composite Science and Technology, vol. 220, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[28] Itzhak Green, and Capel English, “Analysis of Elastomeric O-Ring Seals in Compression Using the Finite Element Method,” Tribology Transactions, vol. 35, no. 1, pp. 83-88, 2008.
[CrossRef] [Google Scholar] [Publisher Link]
[29] Patricia Cazón, Gonzalo Velázquez, and Manuel Vázquez, “Regenerated Cellulose Films Combined with Glycerol and Polyvinyl Alcohol: Effect of Moisture Content on the Physical Properties,” Food Hydrocolloids, vol. 103, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[30] Jun Fu, “Strong and Tough Hydrogels Crosslinked by Multi-Functional Polymer Colloids,” Journal of Polymer Science Part B: Polymer Physics, vol. 59, no. 19, pp. 1336-1250, 2018.
[CrossRef] [Google Scholar] [Publisher Link]
[31] Viviana R. Güiza- Argüello et al., “Current Advances in the Development of Hydrogel-Based Wound Dressings for Diabetic Foot Ulcer Treatment,” Polymers, vol. 14, no. 14, pp. 1-25, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[32] Li Jingcheng et al., “Intelligent Polymers, Fibers and Applications,” Polymers, vol. 13, no. 9, pp. 1-19, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[33] A. Jumahat et al., “Improved Compressive Properties of a Unidirectional CFRP Laminate Using Nanosilica Particles,” Composites and Advanced Materials, vol. 19, no. 6, pp. 204-207, 2010.
[CrossRef] [Google Scholar] [Publisher Link]
[34] Mohammed Zorah et al., “The Promises of The Potential Uses of Polymer Biomaterials in Biomedical Applications and Their Challenges,” International Journal of Applied Pharmaceutic, vol. 15, no. 4, pp. 27-36, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[35] Denis Mihaela Panaitescu et al., “Properties of Polymer Composites with Cellulose Microfibrils,” Molecular Crystals and Liquid Crystals, vol. 484, no. 1, pp. 86/[452]-98/[464], 2008.
[CrossRef] [Google Scholar] [Publisher Link]
[36] M.A. Bay et al., “Mechanical and Thermal Properties of Nanocomposite Films Made of Polyvinyl Alcohol/Nanofiber Cellulose and Nanosilicon Dioxide using Ultrasonic Method,” International Journal of Nanoscience and Nanotechnology, vol. 17, no. 2, pp. 65-76, 2021.
[Google Scholar] [Publisher Link]
[37] Mostafa Y. Ismail et al., “Hybrid Films of Cellulose Nanofibrils, Chitosan and Nanosilica - Structural, Thermal, Optical, and Mechanical Properties,” Carbohydrate Polymers, vol. 218, pp. 87-94, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[38] Sofía Collazo-Bigliardi, Rodrigo Ortega-Toro, and Amparo Chiralt Boix, “Isolation and Characterisation of Microcrystalline Cellulose and Cellulose Nanocrystals from Coffee Husk and Comparative Study with Rice Husk,” Carbohydrate Polymers, vol. 191, pp. 205-215, 2018.
[CrossRef] [Google Scholar] [Publisher Link]
[39] E.T.N. Bisanda, and M.P. Ansell, “The Effect of Silane Treatment on Mechanical and Physical Properties of Sisal-Epoxy Composites,” Composites Science and Technology, vol. 41, no. 2, pp. 165-178, 1991.
[CrossRef] [Google Scholar] [Publisher Link]
[40] Tsuyoshi Tadano et al., “Molecular Weight Dependence of SiO2 Nanoparticle Agglomeration Behavior in Monodisperse PMMA - SiO2 Hybrid Suspension, Chemistry Letters, vol. 46, no. 6, pp. 342-348, 2014.
[CrossRef] [Google Scholar] [Publisher Link]
[41] C.N. Aiza Jaafar et al., “Effects of the Liquid Natural Rubber (LNR) on Mechanical Properties and Microstructure of Epoxy/Silica/Kenaf Hybrid Composite for Potential Automotive Applications,” Journal of Materials Research and Technology, vol. 12, pp. 1026-1038, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[42] M. Smith, Z. Guan, and W.J. Cantwell, “Finite Element Modelling of The Compressive Response of Lattice Structures Manufactured Using the Selective Laser Melting Technique,” International Journal of Mechanical Sciences, vol. 67, pp. 28-41, 2013.
[CrossRef] [Google Scholar] [Publisher Link]
[43] Joshua E. Johnson, and Karen L. Troy, “Validation of a New Multiscale Finite Element Analysis Approach at the Distal Radius,” Medical Engineering and Physics, vol. 44, pp. 16-24, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[44] Dongjun Lee et al., Finite Element Analysis of Reinforced Concrete Walls with Openings in One- And Two-Way Action, Taylor and Francis, 1st ed., 2006.
[Google Scholar] [Publisher Link]
[45] Thomas D. Brown, and Anthony M. Davis, “Contact-Coupled Finite Element Analysis of The Natural Adult Hip,” Journal of Biomechanics, vol. 17, no. 6, pp. 437-448, 2006.
[CrossRef] [Google Scholar] [Publisher Link]