Synthesis, Thermal, Hirschfeld Surface Analysis, and Spectroscopic Properties of a Cd(II) Coordination Polymer with 1-Hydroxy-2-Naphthoic Acid
Synthesis, Thermal, Hirschfeld Surface Analysis, and Spectroscopic Properties of a Cd(II) Coordination Polymer with 1-Hydroxy-2-Naphthoic Acid |
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| © 2025 by IJETT Journal | ||
| Volume-73 Issue-7 |
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| Year of Publication : 2025 | ||
| Author : D.Kh. Saidov, Kh.Kh. Turaev, A.B. Ibragimov, G.Kh. Toirova, Kh.Kh. Kulbasheva | ||
| DOI : 10.14445/22315381/IJETT-V73I7P123 | ||
How to Cite?
D.Kh. Saidov, Kh.Kh. Turaev, A.B. Ibragimov, G.Kh. Toirova, Kh.Kh. Kulbasheva, "Synthesis, Thermal, Hirschfeld Surface Analysis, and Spectroscopic Properties of a Cd(II) Coordination Polymer with 1-Hydroxy-2-Naphthoic Acid," International Journal of Engineering Trends and Technology, vol. 73, no. 7, pp.293-307, 2025. Crossref, https://doi.org/10.14445/22315381/IJETT-V73I7P123
Abstract
In this paper, a new cadmium-based polymer was synthesized using 1-hydroxy-2-naphthoic Acid and cadmium acetate. The structural and physicochemical properties of the obtained polymer were investigated using various analytical techniques. Moreover, Hirshfeld surface analysis was employed to assess intermolecular interactions, while FT-IR and UV-Vis spectroscopy provided insights into the functional groups and electronic transitions. Thermal behavior was examined through Differential Thermal Analysis (DTA) and thermogravimetric analysis (TGA). The crystallinity and phase purity were confirmed by X-Ray Diffraction (XRD) using a Rigaku MiniFlex 600 diffractometer. In addition, elemental composition was determined via CHNS/O analysis (Thermo Scientific FlashSmart), and morphological studies were conducted using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS). Additionally, the polymer’s electrical properties were evaluated through conductometric measurements.
Keywords
Cadmium-based polymer, 1-hydroxy-2-naphthoic Acid, Hirshfeld surface analysis, FT-IR, UV-Vis, XRD, DTA, TGA, CHNS/O analysis, SEM-EDS, Conductometry.
References
[1] Abdullaev Ahrorjon Khabibjonovich et al., “Two Dimensional Coordination Polymer of Pb (II) Complex with M-Sulfanilic Acid: Synthesis, Characterization, Electrical Conductivity, Adsorption Properties and Hirshfeld Surface Analysis,” Adsorption, vol. 31, no. 2, 2025.
[CrossRef] [Google Scholar] [Publisher Link]
[2] Claudio Pettinari et al., “Application of Metal - Organic Frameworks,” Polymer International, vol. 66, no. 6, pp. 731-744, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[3] Fangyu Ren, and Pengfei Ji, “Recent Advances in the Application of Metal - Organic Frameworks for Polymerization and Oligomerization Reactions,” Catalysts, vol. 10, no. 12, pp. 1-25, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[4] Xiang Zhao et al., “Metal - Organic Frameworks for Separation,” Advanced Materials, vol. 30, no. 37, pp. 1-103, 2018.
[CrossRef] [Google Scholar] [Publisher Link]
[5] Bernhard V.K.J. Schmidt, “Metal‐Organic Frameworks in Polymer Science: Polymerization Catalysis, Polymerization Environment, and Hybrid Materials,” Macromolecular Rapid Communications, vol. 41, no. 1, pp. 1-28, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[6] Dimitrios Giliopoulos et al., “Polymer/Metal Organic Framework (MOF) Nanocomposites for Biomedical Applications,” Molecules, vol. 25, no. 1, pp. 1-28, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[7] A. Dieter Schlüter, Thomas Weber, and Gregor Hofer, “How to Use X-ray Diffraction to Elucidate 2D Polymerization Propagation in Single Crystals,” Chemical Society Reviews, vol. 49, no. 15, pp. 5140-5158, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[8] Austin M. Evans et al., “Controlled n‐Doping of Naphthalene‐Diimide‐Based 2D Polymers,” Advanced Materials, vol. 34, no. 22, pp. 1-22, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[9] Liyuan Xiao, Zhenlu Wang, and Jingqi Guan, “2D MOFS and their Derivatives for Electrocatalytic Applications: Recent Advances and New Challenges,” Coordination Chemistry Reviews, vol. 472, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[10] Alexandre Abhervé et al., “Graphene Related Magnetic Materials: Micromechanical Exfoliation of 2D Layered Magnets Based on Bimetallic Anilate Complexes with Inserted [Fe III (acac 2-trien)]+ and [Fe III (sal 2-trien)]+ Molecules,” Chemical Science, vol. 6, no. 8, pp. 4665-4673, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[11] Bingbing Liu et al., “2D MOF with Electrochemical Exfoliated Graphene for Nonenzymatic Glucose Sensing: Central Metal Sites and Oxidation Potentials,” Analytica Chimica Acta, vol. 1122, pp. 9-19, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[12] Sukanya Bhunia, Kaivalya A. Deo, and Akhilesh K. Gaharwar, “2D Covalent Organic Frameworks for Biomedical Applications,” Advanced Functional Materials, vol. 30, no. 27, pp. 1-74, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[13] Pan-Pan Sun et al., “Real‐Time Fluorescent Monitoring of Kinetically Controlled Supramolecular Self‐Assembly of Atom‐Precise Cu8 Nanocluster,” Angewandte Chemie, vol. 135, no. 20, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[14] Xiaoxi Ji et al., “A Water‐Stable Luminescent Sensor Based on Cd2+ Coordination Polymer for Detecting Nitroimidazole Antibiotics in Water,” Applied Organometallic Chemistry, vol. 35, no. 10, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[15] Dr. Yifan Gu et al., “Host–Guest Interaction Modulation in Porous Coordination Polymers for Inverse Selective CO2/C2H2 Separation,” Angewandte Chemie International Edition, vol. 60, no. 21, pp. 11688-11694, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[16] Liangying Li et al., “Discrimination of Xylene Isomers in a Stacked Coordination Polymer,” Science, vol. 367, no. 6603, pp. 335-339, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[17] Zhifen Guo et al., “One-Pot Dual Catalysis of a Photoactive Coordination Polymer and Palladium Acetate for the Highly Efficient Cross-Coupling Reaction via Interfacial Electron Transfer,” Inorganic Chemistry, vol. 61, no. 5, pp. 2695-2705, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[18] Yingbi Chen et al., “High Selectivity and Reusability of Coordination Polymer Adsorbents: Synthesis, Adsorption Properties and Activation Energy,” Microporous and Mesoporous Materials, vol. 324, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[19] Aleksej Jochim et al., “Structural Diversity in Ni Chain Coordination Polymers: Synthesis, Structures, Isomerism and Magnetism,” European Journal of Inorganic Chemistry, vol. 2018, no. 44, pp. 4779-4789, 2018.
[CrossRef] [Google Scholar] [Publisher Link]
[20] Yu-Rong Xi et al., “A Set of Cd-Based Metal Coordination Complexes with a Novel Bis (Hydroxyl Naphthoic Acid) Ligand: Syntheses, Structure and Luminescent Properties,” Structure and Luminescent Properties, pp. 1-25, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[21] Xiao-Ling He et al., “New Photoluminescent Zn (II)/Cd (II) Coordination Polymers for Laryngeal Carcinoma Therapy,” Chemical Papers, vol. 76, no. 5, pp. 2875-2882, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[22] K. Venkataraman, The Chemistry of Synthetic Dyes, Volume V, Academic Press, New York, 1971. [Online]. Available: https://api.pageplace.de/preview/DT0400.9780323142953_A23647633/preview-9780323142953_A23647633.pdf
[23] Shadia A. Elsayed et al., “New Complexes of 2-Hydroxy-1-Naphthoic Acid and X-ray Crystal Structure of [Pt (hna)(PPh3) 2],” Journal of Molecular Structure, vol. 1036, pp. 196-202, 2013.
[CrossRef] [Google Scholar] [Publisher Link]
[24] Yusufjon Eshkobilovich Nazarov et al., “Bis (8-hydroxyquinolinium) Naphthalene-1, 5-Disulfonate Tetrahydrate,” IUCrData, vol. 9, no. 6, 2024.
[CrossRef] [Google Scholar] [Publisher Link]
[25] F.S. Narmanova et al., “Synthesis, Structure, Hirshfeld Surface Analysis, and Molecular Docking Studies of the Cu (II) complex with 3-Nitro-4-Aminobenzoic Acid,” Structural Chemistry, vol.35, no. 5, pp. 1641-1648, 2024.
[CrossRef] [Google Scholar] [Publisher Link]
[26] F.S. Narmanova et al., “The Structure and Hirshfeld Surface Analysis of the 4-Amino 3-Nitrobenzoic Acid Triclinic Polymorph,” Structural Chemistry, vol. 35 no. 3, pp. 953-960, 2024.
[CrossRef] [Google Scholar] [Publisher Link]
[27] Mark A. Spackman, and Dylan Jayatilaka, “Hirshfeld Surface Analysis,” CrystEngComm, vol. 11, no. 1, pp. 19-32, 2009.
[CrossRef] [Google Scholar] [Publisher Link]
[28] Yokubjon Bozorov et al., “Ion Exchange Membranes in Environmental Applications: Comprehensive Review,” Chemosphere, vol. 377, 2025.
[CrossRef] [Google Scholar] [Publisher Link]
[29] Abror Nomozov et al., “Synthesis of Corrosion Inhibitors Based on (Thio)Urea, Orthophosphoric Acid and Formaldehyde and their Inhibition Efficiency,” Baghdad Science Journal, vol. 22, no. 4, pp. 1-15, 2025.
[CrossRef] [Google Scholar] [Publisher Link]
[30] Mokhichekhra Shaymardanova et al., “Studying of The Process of Obtaining Monocalcium Phosphate based on Extraction Phosphoric Acid from Phosphorites of Central Kyzylkum,” Baghdad Science Journal, vol. 21, no. 12, pp. 1-21, 2024.
[CrossRef] [Google Scholar] [Publisher Link]
[31] Abror Kh. Ruzmetov et al., “Synthesis, Crystal Structure and Hirshfeld Surface Analysis of Binuclear Cu (II) Complexes from O/P-Hydroxybenzoic Acid with Ethanol and Water Solution of Monoethanolamine,” Polyhedron, vol. 242, 2023.
[CrossRef] [Google Scholar] [Publisher Link]